Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate
In the title compound, [Pd(C17H14N3S2)2]·2C3H7NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The PdII ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-plana...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810051780 |
| Summary: | In the title compound, [Pd(C17H14N3S2)2]·2C3H7NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The PdII ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethylformamide (DMF) solvent molecules via an N—H...O interaction. In addition, C—H...S interactions are observed. |
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| ISSN: | 1600-5368 |