Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate

Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate

The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diaminodicyclohexylmethane in methanol. The [Zn2Cl6(C8H4O4)]4− anions lie on centres of inversion and comprise two ZnCl3 grou...

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Main Authors: Chun-Wei Yeh, Chi-Phi Wu, Chia-Her Lin, Jhy-Der Chen, Chen-Yen Hsu
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808033011
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spelling doaj-bbe77ca933304d1f8be10b99e31d9f252020-11-24T21:32:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1412m141210.1107/S1600536808033011Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrateChun-Wei YehChi-Phi WuChia-Her LinJhy-Der ChenChen-Yen HsuThe title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diaminodicyclohexylmethane in methanol. The [Zn2Cl6(C8H4O4)]4− anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxylate. In addition to N—H...Cl and N—H...O hydrogen bonds between the cations and anions, solvent water molecules form O—H...O and O—H...Cl hydrogen bonds to give a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808033011
collection DOAJ
language English
format Article
sources DOAJ
author Chun-Wei Yeh
Chi-Phi Wu
Chia-Her Lin
Jhy-Der Chen
Chen-Yen Hsu
spellingShingle Chun-Wei Yeh
Chi-Phi Wu
Chia-Her Lin
Jhy-Der Chen
Chen-Yen Hsu
Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate
Acta Crystallographica Section E
author_facet Chun-Wei Yeh
Chi-Phi Wu
Chia-Her Lin
Jhy-Der Chen
Chen-Yen Hsu
author_sort Chun-Wei Yeh
title Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate
title_short Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate
title_full Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate
title_fullStr Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate
title_full_unstemmed Bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(II)] tetrahydrate
title_sort bis(4,4′-methylenedicyclohexylaminium) μ-benzene-1,4-dicarboxylato-bis[trichloridozinc(ii)] tetrahydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-11-01
description The title compound, (C13H28N2)2[Zn2(C8H4O4)Cl6]·4H2O, was prepared by the reaction of ZnCl2·6H2O, benzene-1,4-dicarboxylic acid and 4,4′-diaminodicyclohexylmethane in methanol. The [Zn2Cl6(C8H4O4)]4− anions lie on centres of inversion and comprise two ZnCl3 groups bridged by benzene-1,4-dicarboxylate. In addition to N—H...Cl and N—H...O hydrogen bonds between the cations and anions, solvent water molecules form O—H...O and O—H...Cl hydrogen bonds to give a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808033011
work_keys_str_mv AT chunweiyeh bis448242methylenedicyclohexylaminium956benzene14dicarboxylatobistrichloridozinciitetrahydrate
AT chiphiwu bis448242methylenedicyclohexylaminium956benzene14dicarboxylatobistrichloridozinciitetrahydrate
AT chiaherlin bis448242methylenedicyclohexylaminium956benzene14dicarboxylatobistrichloridozinciitetrahydrate
AT jhyderchen bis448242methylenedicyclohexylaminium956benzene14dicarboxylatobistrichloridozinciitetrahydrate
AT chenyenhsu bis448242methylenedicyclohexylaminium956benzene14dicarboxylatobistrichloridozinciitetrahydrate
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