The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]

The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]

The title complex, dichlorido[N,N-dimethyl-2-(η5-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C13H20N2)Cl2], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C&#821...

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Bibliographic Details
Main Authors: Donglong Guo, Hong-Bo Tong, Meisu Zhou
Format: Article
Language:English
Published: International Union of Crystallography 2009-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809015839
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spelling doaj-bb996c2ac4f64ba1ad2155aabd8d91ea2020-11-25T01:58:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m611m61110.1107/S1600536809015839The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]Donglong GuoHong-Bo TongMeisu ZhouThe title complex, dichlorido[N,N-dimethyl-2-(η5-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C13H20N2)Cl2], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)°. http://scripts.iucr.org/cgi-bin/paper?S1600536809015839
collection DOAJ
language English
format Article
sources DOAJ
author Donglong Guo
Hong-Bo Tong
Meisu Zhou
spellingShingle Donglong Guo
Hong-Bo Tong
Meisu Zhou
The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]
Acta Crystallographica Section E
author_facet Donglong Guo
Hong-Bo Tong
Meisu Zhou
author_sort Donglong Guo
title The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]
title_short The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]
title_full The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]
title_fullStr The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]
title_full_unstemmed The ansa-bridged cyclopentadienyl titanium complex [{η5-C5Me4CH2-C(NMe2)=N}TiCl2]
title_sort ansa-bridged cyclopentadienyl titanium complex [{η5-c5me4ch2-c(nme2)=n}ticl2]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-06-01
description The title complex, dichlorido[N,N-dimethyl-2-(η5-tetramethylcyclopentadienyl)acetamidinido-κN′]titanium(IV), [Ti(C13H20N2)Cl2], exhibits an unusual ansa-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809015839
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