Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)]
In the title complex, [La2(C10H10NO3)2(NO3)4(C12H8N2)4], each LaIII ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenylglycinate ligands and four from two nitrate anions. Two LaIII cations, which exhibit a distorted...
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| Language: | English |
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International Union of Crystallography
2009-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808038075 |
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doaj-bb67f1bdddea496d970303a2f8e0a9a22020-11-25T01:04:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m59m5910.1107/S1600536808038075Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)]Xiaonan GaoIn the title complex, [La2(C10H10NO3)2(NO3)4(C12H8N2)4], each LaIII ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenylglycinate ligands and four from two nitrate anions. Two LaIII cations, which exhibit a distorted bicapped square-antiprismatic coordination, are bridged by two N-acetyl-N-phenylglycinate ligands into a dimeric structure, generated by inversion symmetry. There is a π–π contact between the benzene rings [centroid–centroid distance = 3.409 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536808038075 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Xiaonan Gao |
| spellingShingle |
Xiaonan Gao Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)] Acta Crystallographica Section E |
| author_facet |
Xiaonan Gao |
| author_sort |
Xiaonan Gao |
| title |
Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)] |
| title_short |
Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)] |
| title_full |
Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)] |
| title_fullStr |
Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)] |
| title_full_unstemmed |
Bis(μ-N-acetyl-N-phenylglycinato-κ2O:O′)bis[dinitrato-κ4O,O′-bis(1,10-phenanthroline-κ2N,N′)lanthanum(III)] |
| title_sort |
bis(μ-n-acetyl-n-phenylglycinato-κ2o:o′)bis[dinitrato-κ4o,o′-bis(1,10-phenanthroline-κ2n,n′)lanthanum(iii)] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-01-01 |
| description |
In the title complex, [La2(C10H10NO3)2(NO3)4(C12H8N2)4], each LaIII ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenylglycinate ligands and four from two nitrate anions. Two LaIII cations, which exhibit a distorted bicapped square-antiprismatic coordination, are bridged by two N-acetyl-N-phenylglycinate ligands into a dimeric structure, generated by inversion symmetry. There is a π–π contact between the benzene rings [centroid–centroid distance = 3.409 (3) Å]. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808038075 |
| work_keys_str_mv |
AT xiaonangao bis956nacetylnphenylglycinato9542oo8242bisdinitrato9544oo8242bis110phenanthroline9542nn8242lanthanumiii |
| _version_ |
1725197274988937216 |