Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation

Exploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity...

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Main Authors:	Xiuquan Jia, Jiping Ma, Fei Xia, Mingxia Gao, Jin Gao, Jie Xu
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-05-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-10315-9

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spelling	doaj-bb5cd324d0c04ac7ad40dc8a20a29d892021-05-11T11:27:55ZengNature Publishing GroupNature Communications2041-17232019-05-011011710.1038/s41467-019-10315-9Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidationXiuquan Jia0Jiping Ma1Fei Xia2Mingxia Gao3Jin Gao4Jie Xu5State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesExploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity of structurally diverse arylmethyl amines.https://doi.org/10.1038/s41467-019-10315-9
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Xiuquan Jia Jiping Ma Fei Xia Mingxia Gao Jin Gao Jie Xu
spellingShingle	Xiuquan Jia Jiping Ma Fei Xia Mingxia Gao Jin Gao Jie Xu Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation Nature Communications
author_facet	Xiuquan Jia Jiping Ma Fei Xia Mingxia Gao Jin Gao Jie Xu
author_sort	Xiuquan Jia
title	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_short	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_full	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_fullStr	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_full_unstemmed	Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
title_sort	switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-05-01
description	Exploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity of structurally diverse arylmethyl amines.
url	https://doi.org/10.1038/s41467-019-10315-9
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Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation

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