Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)

Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)

In the title compound, [Sn(C6H11)2(C13H15NO4)], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC2O2 geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O′-tridentate ligand. The two cyclohex...

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Main Authors: Hong-Jun Yang, Yan-Qiu Dang
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809008393
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spelling doaj-bb54957988aa47139334450bbe2b53de2020-11-24T22:09:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m398m39910.1107/S1600536809008393Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)Hong-Jun YangYan-Qiu DangIn the title compound, [Sn(C6H11)2(C13H15NO4)], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC2O2 geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O′-tridentate ligand. The two cyclohexyl groups bound to the Sn atom adopt chair conformations, with the Sn—C bonds in equatorial positions and a mean Sn—C distance of 2.138 (3) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536809008393
collection DOAJ
language English
format Article
sources DOAJ
author Hong-Jun Yang
Yan-Qiu Dang
spellingShingle Hong-Jun Yang
Yan-Qiu Dang
Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)
Acta Crystallographica Section E
author_facet Hong-Jun Yang
Yan-Qiu Dang
author_sort Hong-Jun Yang
title Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)
title_short Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)
title_full Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)
title_fullStr Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)
title_full_unstemmed Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ3O,N,O′]tin(IV)
title_sort dicyclohexyl[n-(3-methoxy-2-oxidobenzylidene)valinato-κ3o,n,o′]tin(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description In the title compound, [Sn(C6H11)2(C13H15NO4)], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC2O2 geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O′-tridentate ligand. The two cyclohexyl groups bound to the Sn atom adopt chair conformations, with the Sn—C bonds in equatorial positions and a mean Sn—C distance of 2.138 (3) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809008393
work_keys_str_mv AT hongjunyang dicyclohexyln3methoxy2oxidobenzylidenevalinatoamp9543onoamp8242tiniv
AT yanqiudang dicyclohexyln3methoxy2oxidobenzylidenevalinatoamp9543onoamp8242tiniv
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