catena-Poly[bis(μ3-3-aminobenzoato-κ4N:O:O,O′)bis(μ2-3-aminobenzoato-κ3O,O′:O)dilead(II)]
The PbII atom in the title compound, {[Pb2(C7H6NO2)4]}n, is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitrogen donor and one oxygen donor in the axial positions. Two molecules are linke...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810041322 |
| Summary: | The PbII atom in the title compound, {[Pb2(C7H6NO2)4]}n, is chelated by two 3-aminobenzoato ligands in a distorted pentagonal-bipyramidal coordination geometry with five oxygen donors in the equatorial positions, one nitrogen donor and one oxygen donor in the axial positions. Two molecules are linked through a centre of inversion, forming a dinuclear entity. These entities are linked in a μ3-bridging mode through the amino N atom and two carboxylate O atoms into a chain along the b axis. Classical intermolecular N—H...O hydrogen bonding is observed in the structure. The supramolecular structure is consolidated by π–π stacking interactions with centroid–centroid distances between benzene rings of 3.837 (8) Å. |
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| ISSN: | 1600-5368 |