Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate

Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate

The PdII ion in the title compound, [Pd(C17H14N3S2)2]·2C5H5N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.1...

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Main Authors: Hamid Khaledi, Hapipah Mohd Ali
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811001991
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spelling doaj-bb3fae17fcd54fac8f2b18c8ddc074552020-11-24T21:27:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m230m23010.1107/S1600536811001991Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvateHamid KhalediHapipah Mohd AliThe PdII ion in the title compound, [Pd(C17H14N3S2)2]·2C5H5N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent molecules via an N—H...N interaction. The crystal structure is consolidated by intermolecular C—H...S interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536811001991
collection DOAJ
language English
format Article
sources DOAJ
author Hamid Khaledi
Hapipah Mohd Ali
spellingShingle Hamid Khaledi
Hapipah Mohd Ali
Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
Acta Crystallographica Section E
author_facet Hamid Khaledi
Hapipah Mohd Ali
author_sort Hamid Khaledi
title Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
title_short Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
title_full Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
title_fullStr Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
title_full_unstemmed Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
title_sort bis{benzyl 3-[(1h-indol-3-yl)methylidene]dithiocarbazato-κ2n3,s}palladium(ii) pyridine disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-02-01
description The PdII ion in the title compound, [Pd(C17H14N3S2)2]·2C5H5N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent molecules via an N—H...N interaction. The crystal structure is consolidated by intermolecular C—H...S interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811001991
work_keys_str_mv AT hamidkhaledi bisbenzyl31hindol3ylmethylidenedithiocarbazatoamp9542n3spalladiumiipyridinedisolvate
AT hapipahmohdali bisbenzyl31hindol3ylmethylidenedithiocarbazatoamp9542n3spalladiumiipyridinedisolvate
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