Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate
The PdII ion in the title compound, [Pd(C17H14N3S2)2]·2C5H5N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.1...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811001991 |
| Summary: | The PdII ion in the title compound, [Pd(C17H14N3S2)2]·2C5H5N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent molecules via an N—H...N interaction. The crystal structure is consolidated by intermolecular C—H...S interactions. |
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| ISSN: | 1600-5368 |