(Chlorido/bromido)[(1,2,5,6-η)-cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)rhodium(I)

(Chlorido/bromido)[(1,2,5,6-η)-cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)rhodium(I)

A new triazole-based neutral RhI complex, [Rh(Cl0.846Br0.154)(C6H11N3)(C8H12)], has been synthesized and structurally characterized. The RhI atom has a distorted square-planar coordination environment, formed by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide lig...

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Bibliographic Details
Main Authors: Joshua Rushlow, Andrei V. Astashkin, Daniel R. Albert, Edward Rajaseelan
Format: Article
Language:English
Published: International Union of Crystallography 2021-08-01
Series:IUCrData
Subjects:
crystal structure
rhodium
n-heterocyclic carbenes
cl/br substitutional disorder
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314621008117

Internet

http://scripts.iucr.org/cgi-bin/paper?S2414314621008117

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