Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling
Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique...
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Nature Publishing Group
2017-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-01934-1 |
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doaj-bae30ce09492472a96d838a85983c9542021-05-11T07:32:55ZengNature Publishing GroupNature Communications2041-17232017-12-01811710.1038/s41467-017-01934-1Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocouplingXiao-Ye Wang0Marcus Richter1Yuanqin He2Jonas Björk3Alexander Riss4Raju Rajesh5Manuela Garnica6Felix Hennersdorf7Jan J. Weigand8Akimitsu Narita9Reinhard Berger10Xinliang Feng11Willi Auwärter12Johannes V. Barth13Carlos-Andres Palma14Klaus Müllen15Max Planck Institute for Polymer Research, Ackermannweg 10Department for Molecular Functional Materials, Center for Advancing Electronics Dresden (cfaed), Dresden University of Technology, Mommsenstr. 4Institute for Advanced Study, Technical University of Munich, Lichtenbergstr. 2aDepartment of Physics, Chemistry and Biology, IFM, Linköping UniversityPhysik-Department E20, Technical University of Munich, James-Franck-Str. 1Max Planck Institute for Polymer Research, Ackermannweg 10Physik-Department E20, Technical University of Munich, James-Franck-Str. 1Chair of Inorganic Molecular Chemistry, Dresden University of Technology, Mommsenstr. 4Chair of Inorganic Molecular Chemistry, Dresden University of Technology, Mommsenstr. 4Max Planck Institute for Polymer Research, Ackermannweg 10Department for Molecular Functional Materials, Center for Advancing Electronics Dresden (cfaed), Dresden University of Technology, Mommsenstr. 4Department for Molecular Functional Materials, Center for Advancing Electronics Dresden (cfaed), Dresden University of Technology, Mommsenstr. 4Physik-Department E20, Technical University of Munich, James-Franck-Str. 1Physik-Department E20, Technical University of Munich, James-Franck-Str. 1Physik-Department E20, Technical University of Munich, James-Franck-Str. 1Max Planck Institute for Polymer Research, Ackermannweg 10Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character.https://doi.org/10.1038/s41467-017-01934-1 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen |
| spellingShingle |
Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling Nature Communications |
| author_facet |
Xiao-Ye Wang Marcus Richter Yuanqin He Jonas Björk Alexander Riss Raju Rajesh Manuela Garnica Felix Hennersdorf Jan J. Weigand Akimitsu Narita Reinhard Berger Xinliang Feng Willi Auwärter Johannes V. Barth Carlos-Andres Palma Klaus Müllen |
| author_sort |
Xiao-Ye Wang |
| title |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
| title_short |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
| title_full |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
| title_fullStr |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
| title_full_unstemmed |
Exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
| title_sort |
exploration of pyrazine-embedded antiaromatic polycyclic hydrocarbons generated by solution and on-surface azomethine ylide homocoupling |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2017-12-01 |
| description |
Polyaromatic hydrocarbons can be precisely manipulated to yield ever more complex and discrete graphene analogs, such as nanographenes. Here, the authors use azomethine ylide homocoupling to insert an antiaromatic pyrazine ring into the core of a nanographene, and characterize the molecule’s unique electronic character. |
| url |
https://doi.org/10.1038/s41467-017-01934-1 |
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