Synthesis and Characterization of Barium Hexafluoridoosmates
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with t...
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MDPI AG
2017-12-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/8/1/11 |
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doaj-badd74d70b7c415b9a007a81f5b6821a2020-11-24T22:05:33ZengMDPI AGCrystals2073-43522017-12-01811110.3390/cryst8010011cryst8010011Synthesis and Characterization of Barium HexafluoridoosmatesSergei I. Ivlev0Antti J. Karttunen1Magnus R. Buchner2Matthias Conrad3Roman V. Ostvald4Florian Kraus5Fachbereich Chemie, Philipps-Universität Marburg, 35032 Marburg, GermanyDepartment of Chemistry and Materials Science, Aalto University, 00076 Aalto, FinlandFachbereich Chemie, Philipps-Universität Marburg, 35032 Marburg, GermanyFachbereich Chemie, Philipps-Universität Marburg, 35032 Marburg, GermanyInstitute of Applied Physics and Technology, Tomsk Polytechnic University, Tomsk 634050, RussiaFachbereich Chemie, Philipps-Universität Marburg, 35032 Marburg, GermanyTwo barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6 crystallizes in the space group type R 3 ¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2.https://www.mdpi.com/2073-4352/8/1/11osmiumfluoridesbromine trifluoridecrystal structure |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Sergei I. Ivlev Antti J. Karttunen Magnus R. Buchner Matthias Conrad Roman V. Ostvald Florian Kraus |
| spellingShingle |
Sergei I. Ivlev Antti J. Karttunen Magnus R. Buchner Matthias Conrad Roman V. Ostvald Florian Kraus Synthesis and Characterization of Barium Hexafluoridoosmates Crystals osmium fluorides bromine trifluoride crystal structure |
| author_facet |
Sergei I. Ivlev Antti J. Karttunen Magnus R. Buchner Matthias Conrad Roman V. Ostvald Florian Kraus |
| author_sort |
Sergei I. Ivlev |
| title |
Synthesis and Characterization of Barium Hexafluoridoosmates |
| title_short |
Synthesis and Characterization of Barium Hexafluoridoosmates |
| title_full |
Synthesis and Characterization of Barium Hexafluoridoosmates |
| title_fullStr |
Synthesis and Characterization of Barium Hexafluoridoosmates |
| title_full_unstemmed |
Synthesis and Characterization of Barium Hexafluoridoosmates |
| title_sort |
synthesis and characterization of barium hexafluoridoosmates |
| publisher |
MDPI AG |
| series |
Crystals |
| issn |
2073-4352 |
| publishDate |
2017-12-01 |
| description |
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6 crystallizes in the space group type R 3 ¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2. |
| topic |
osmium fluorides bromine trifluoride crystal structure |
| url |
https://www.mdpi.com/2073-4352/8/1/11 |
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