Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production

Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production

A new copper-based supramolecular (β-cyclodextrins, β-CD) catalyst was synthesized and used for transesterification of Xanthium sibiricum Patr oil to biodiesel. This catalyst exhibited high activity (88.63% FAME yield) in transesterification under the ratio of methanol-oil: 40 : 1; catalyst dosage:...

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Main Authors: Fei Chang, Chen Yan, Quan Zhou
Format: Article
Language:English
Published: Hindawi Limited 2018-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2018/7452817
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spelling doaj-bab67c15b5e04322a19a47bd047e3cd42021-07-02T06:20:59ZengHindawi LimitedInternational Journal of Chemical Engineering1687-806X1687-80782018-01-01201810.1155/2018/74528177452817Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel ProductionFei Chang0Chen Yan1Quan Zhou2Institute of Comprehensive Utilization of Plant Resources, Kaili University, Kaili 556011, ChinaAn Shun City People’s Hospital, People’s Hospital Republic of China, An Shun 561000, ChinaPharmaceutical and Bioengineering College, Hunan Chemical Vocational Technology College, Zhuzhou, Hunan 412000, ChinaA new copper-based supramolecular (β-cyclodextrins, β-CD) catalyst was synthesized and used for transesterification of Xanthium sibiricum Patr oil to biodiesel. This catalyst exhibited high activity (88.63% FAME yield) in transesterification under the ratio of methanol-oil: 40 : 1; catalyst dosage: 8 wt.%; reaction temperature: 120°C; and reaction time: 9 h. The XRD, SEM, TEM, XPS, and BET characterization results showed that Cu-β-CD catalyst was amorphous and had clear mesoporous structure (17.2 nm) as compared with the native β-CD. This phenomenon is attributed to the coordination of Cu and β-CD.http://dx.doi.org/10.1155/2018/7452817
collection DOAJ
language English
format Article
sources DOAJ
author Fei Chang
Chen Yan
Quan Zhou
spellingShingle Fei Chang
Chen Yan
Quan Zhou
Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production
International Journal of Chemical Engineering
author_facet Fei Chang
Chen Yan
Quan Zhou
author_sort Fei Chang
title Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production
title_short Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production
title_full Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production
title_fullStr Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production
title_full_unstemmed Synthesis of a New Copper-Based Supramolecular Catalyst and Its Catalytic Performance for Biodiesel Production
title_sort synthesis of a new copper-based supramolecular catalyst and its catalytic performance for biodiesel production
publisher Hindawi Limited
series International Journal of Chemical Engineering
issn 1687-806X
1687-8078
publishDate 2018-01-01
description A new copper-based supramolecular (β-cyclodextrins, β-CD) catalyst was synthesized and used for transesterification of Xanthium sibiricum Patr oil to biodiesel. This catalyst exhibited high activity (88.63% FAME yield) in transesterification under the ratio of methanol-oil: 40 : 1; catalyst dosage: 8 wt.%; reaction temperature: 120°C; and reaction time: 9 h. The XRD, SEM, TEM, XPS, and BET characterization results showed that Cu-β-CD catalyst was amorphous and had clear mesoporous structure (17.2 nm) as compared with the native β-CD. This phenomenon is attributed to the coordination of Cu and β-CD.
url http://dx.doi.org/10.1155/2018/7452817
work_keys_str_mv AT feichang synthesisofanewcopperbasedsupramolecularcatalystanditscatalyticperformanceforbiodieselproduction
AT chenyan synthesisofanewcopperbasedsupramolecularcatalystanditscatalyticperformanceforbiodieselproduction
AT quanzhou synthesisofanewcopperbasedsupramolecularcatalystanditscatalyticperformanceforbiodieselproduction
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