Design and synthesis of chemically complex ceramics from the perspective of entropy
High-entropy ceramics (HECs) have rapidly expanded from high-entropy oxides to high-entropy ultrahigh temperature ceramics/coatings and have drawn extensive attention in the field of ceramics. In addition, high-entropy thermoelectric materials focus on the topic of energy, which is another major dri...
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doaj-baa3af185ad94abca533c9697fbc4a002020-12-23T05:04:04ZengElsevierMaterials Today Advances2590-04982020-12-018100114Design and synthesis of chemically complex ceramics from the perspective of entropyJ. Liu0G. Shao1D. Liu2K. Chen3K. Wang4B. Ma5K. Ren6Y. Wang7State Key Laboratory of Traction Power & School of Mechanics and Engineering, Southwest Jiaotong University, Chengdu, Sichuan 610031, China; Corresponding author.School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, ChinaSchool of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, Sichuan 610031, ChinaSchool of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing, 102206, ChinaSchool of Mechanical Engineering, Dongguan University of Technology, Dongguan, Guangdong, 523808, ChinaSchool of Mechanical Engineering, Dongguan University of Technology, Dongguan, Guangdong, 523808, ChinaInstitute of Advanced Structure Technology, Beijing Institute of Technology, Haidian District, Beijing, 100081, ChinaInstitute of Advanced Structure Technology, Beijing Institute of Technology, Haidian District, Beijing, 100081, China; Corresponding author.High-entropy ceramics (HECs) have rapidly expanded from high-entropy oxides to high-entropy ultrahigh temperature ceramics/coatings and have drawn extensive attention in the field of ceramics. In addition, high-entropy thermoelectric materials focus on the topic of energy, which is another major driving force to accelerate the development of HECs. In this review, the recent progress on the design and synthesis of chemically complex ceramics is summarized. The fundamental understanding of configurational entropy, phase stability, and formation criterion of HECs are discussed. Critical comments on the compositionally complex ceramics and mixed-valence complex ceramics are presented. The synthesis methods of HECs are summarized, and reactive flash sintering is highlighted as a new strategy to synthesize HECs. The new design ideas and synthesis methods can provide more opportunities to develop high-performance HECs to meet the requirements of cutting-edge applications.http://www.sciencedirect.com/science/article/pii/S2590049820300618High-entropy ceramicsConfigurational entropyMulticomponentOxidesAliovalent cationFlash sintering |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
J. Liu G. Shao D. Liu K. Chen K. Wang B. Ma K. Ren Y. Wang |
spellingShingle |
J. Liu G. Shao D. Liu K. Chen K. Wang B. Ma K. Ren Y. Wang Design and synthesis of chemically complex ceramics from the perspective of entropy Materials Today Advances High-entropy ceramics Configurational entropy Multicomponent Oxides Aliovalent cation Flash sintering |
author_facet |
J. Liu G. Shao D. Liu K. Chen K. Wang B. Ma K. Ren Y. Wang |
author_sort |
J. Liu |
title |
Design and synthesis of chemically complex ceramics from the perspective of entropy |
title_short |
Design and synthesis of chemically complex ceramics from the perspective of entropy |
title_full |
Design and synthesis of chemically complex ceramics from the perspective of entropy |
title_fullStr |
Design and synthesis of chemically complex ceramics from the perspective of entropy |
title_full_unstemmed |
Design and synthesis of chemically complex ceramics from the perspective of entropy |
title_sort |
design and synthesis of chemically complex ceramics from the perspective of entropy |
publisher |
Elsevier |
series |
Materials Today Advances |
issn |
2590-0498 |
publishDate |
2020-12-01 |
description |
High-entropy ceramics (HECs) have rapidly expanded from high-entropy oxides to high-entropy ultrahigh temperature ceramics/coatings and have drawn extensive attention in the field of ceramics. In addition, high-entropy thermoelectric materials focus on the topic of energy, which is another major driving force to accelerate the development of HECs. In this review, the recent progress on the design and synthesis of chemically complex ceramics is summarized. The fundamental understanding of configurational entropy, phase stability, and formation criterion of HECs are discussed. Critical comments on the compositionally complex ceramics and mixed-valence complex ceramics are presented. The synthesis methods of HECs are summarized, and reactive flash sintering is highlighted as a new strategy to synthesize HECs. The new design ideas and synthesis methods can provide more opportunities to develop high-performance HECs to meet the requirements of cutting-edge applications. |
topic |
High-entropy ceramics Configurational entropy Multicomponent Oxides Aliovalent cation Flash sintering |
url |
http://www.sciencedirect.com/science/article/pii/S2590049820300618 |
work_keys_str_mv |
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