Triazido[tris(2-pyridyl-κN)methylamine]cobalt(III)
The title compound, [Co(N3)3(C16H14N4)], was synthesized by hydrothermal reaction of [Co(NH3)6](NO3)3, NaN3 and tris(2-pyridyl)methylamine. The structure contains two independent complexes in the asymmetric unit, with closely comparable geometry. The CoIII atoms are hexacoordinated by three N atoms...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808035162 |
| Summary: | The title compound, [Co(N3)3(C16H14N4)], was synthesized by hydrothermal reaction of [Co(NH3)6](NO3)3, NaN3 and tris(2-pyridyl)methylamine. The structure contains two independent complexes in the asymmetric unit, with closely comparable geometry. The CoIII atoms are hexacoordinated by three N atoms from the tridentate tris(2-pyridyl)methylamine ligands and three azide ions in a fac arrangement. N—H...N hydrogen bonds are formed between the amino group and the uncoordinated terminal N atoms of the azide ligands. |
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| ISSN: | 1600-5368 |