Ultrafast electron diffraction from a Bi(111) surface: Impulsive lattice excitation and Debye–Waller analysis at large momentum transfer

• Main Authors: V. Tinnemann, C. Streubühr, B. Hafke, A. Kalus, A. Hanisch-Blicharski, M. Ligges, P. Zhou, D. von der Linde, U. Bovensiepen, M. Horn-von Hoegen
• Format: Article
• Language: English
• Published: AIP Publishing LLC and ACA 2019-05-01
• Series: Structural Dynamics
• Online Access: http://dx.doi.org/10.1063/1.5093637

The lattice response of a Bi(111) surface upon impulsive femtosecond laser excitation is studied with time-resolved reflection high-energy electron diffraction. We employ a Debye–Waller analysis at large momentum transfer of 9.3 Å−1 ≤ Δ k ≤ 21.8 Å−1 in order to study the lattice excitation dynamics of the Bi surface under conditions of weak optical excitation up to 2 mJ/cm2 incident pump fluence. The observed time constants τint of decay of diffraction spot intensity depend on the momentum transfer Δk and range from 5 to 12 ps. This large variation of τint is caused by the nonlinearity of the exponential function in the Debye–Waller factor and has to be taken into account for an intensity drop ΔI > 0.2. An analysis of more than 20 diffraction spots with a large variation in Δk gave a consistent value for the time constant τT of vibrational excitation of the surface lattice of 12 ± 1 ps independent on the excitation density. We found no evidence for a deviation from an isotropic Debye–Waller effect and conclude that the primary laser excitation leads to thermal lattice excitation, i.e., heating of the Bi surface.