Histamine perchlorate

Histamine perchlorate

The perchlorate salt of the histamine dication [systematic name: 4-(2-azaniumylethyl)-1H-imidazol-3-ium bis(perchlorate)], C5H11N32+·2ClO4−, crystallizes in the monoclinic space group P21/c with two formula units in the asymmetric unit. One of the histamine dications is disordered [occupancies of 0....

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Main Authors: Ugochukwu Okeke, Yilma Gultneh, Jerry P. Jasinski, Ray J. Butcher
Format: Article
Language:English
Published: International Union of Crystallography 2016-09-01
Series:IUCrData
Subjects:
crystal structure
histamine dication
perchlorate salt
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616014814
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spelling doaj-ba5a89a514ac478bb5b2f6899334f4ba2020-11-25T01:47:09ZengInternational Union of CrystallographyIUCrData2414-31462016-09-0119x16148110.1107/S2414314616014814hg4015Histamine perchlorateUgochukwu Okeke0Yilma Gultneh1Jerry P. Jasinski2Ray J. Butcher3Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USADepartment of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USADepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435, USADepartment of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USAThe perchlorate salt of the histamine dication [systematic name: 4-(2-azaniumylethyl)-1H-imidazol-3-ium bis(perchlorate)], C5H11N32+·2ClO4−, crystallizes in the monoclinic space group P21/c with two formula units in the asymmetric unit. One of the histamine dications is disordered [occupancies of 0.718 (4) and 0.282 (4)] and two of the four perchlorate anions are disordered [occupancies of 0.735 (6):0.265 (6) and 0.637 (5):0.363 (5)]. There is extensive hydrogen bonding in the structure involving both N—H...O and C—H...O interactions, which link the histamine dications and perchlorate anions into a three-dimensional array.http://scripts.iucr.org/cgi-bin/paper?S2414314616014814crystal structurehistamine dicationperchlorate salt
collection DOAJ
language English
format Article
sources DOAJ
author Ugochukwu Okeke
Yilma Gultneh
Jerry P. Jasinski
Ray J. Butcher
spellingShingle Ugochukwu Okeke
Yilma Gultneh
Jerry P. Jasinski
Ray J. Butcher
Histamine perchlorate
IUCrData
crystal structure
histamine dication
perchlorate salt
author_facet Ugochukwu Okeke
Yilma Gultneh
Jerry P. Jasinski
Ray J. Butcher
author_sort Ugochukwu Okeke
title Histamine perchlorate
title_short Histamine perchlorate
title_full Histamine perchlorate
title_fullStr Histamine perchlorate
title_full_unstemmed Histamine perchlorate
title_sort histamine perchlorate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-09-01
description The perchlorate salt of the histamine dication [systematic name: 4-(2-azaniumylethyl)-1H-imidazol-3-ium bis(perchlorate)], C5H11N32+·2ClO4−, crystallizes in the monoclinic space group P21/c with two formula units in the asymmetric unit. One of the histamine dications is disordered [occupancies of 0.718 (4) and 0.282 (4)] and two of the four perchlorate anions are disordered [occupancies of 0.735 (6):0.265 (6) and 0.637 (5):0.363 (5)]. There is extensive hydrogen bonding in the structure involving both N—H...O and C—H...O interactions, which link the histamine dications and perchlorate anions into a three-dimensional array.
topic crystal structure
histamine dication
perchlorate salt
url http://scripts.iucr.org/cgi-bin/paper?S2414314616014814
work_keys_str_mv AT ugochukwuokeke histamineperchlorate
AT yilmagultneh histamineperchlorate
AT jerrypjasinski histamineperchlorate
AT rayjbutcher histamineperchlorate
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