New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers

Thermotropic polymeric tissues have attracted considerable scientific interest for their useful biomedical applications. The complex coupling of van der Waals and steric interactions influences the thermal response of polymers’ molecular structure. Comprehensive theories that govern the molecular re...

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Main Author: Ebtisam A. Aldaais
Format: Article
Language:English
Published: Elsevier 2019-08-01
Series:Results in Materials
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590048X19300135
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spelling doaj-b971fecc97564dd68ac8c29480c6b33d2020-11-25T03:06:09ZengElsevierResults in Materials2590-048X2019-08-011100013New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymersEbtisam A. Aldaais0Department of Biomedical Engineering, College of Engineering, Imam Abdulrahman Bin Faisal University, P. O. Box 1982, Dammam 31451, Saudi ArabiaThermotropic polymeric tissues have attracted considerable scientific interest for their useful biomedical applications. The complex coupling of van der Waals and steric interactions influences the thermal response of polymers’ molecular structure. Comprehensive theories that govern the molecular reorganization define the intramolecular interactions as the interactions between segments of the same polymer, and intermolecular interactions as the interactions between different polymers' segments of differ. The attractive interactions between polymer segments are determined via exact calculations of the intramolecular interactions, while the intermolecular interactions are treated with a self-consistent approximation, which leads to the double counting of the intermolecular interactions. Our decoupled self-consistent field theory (SCF) corrects for that double counting. The results show that the decoupled SCF theory considers less attractive energy than the standard one. These results improve the calculations of several parameters, such as the polymers end-to-end distance, and distinguish the critical parameters that lead to the formation of micelles.http://www.sciencedirect.com/science/article/pii/S2590048X19300135Thermotropic polymersDecoupled SCF theoryPolymer physics
collection DOAJ
language English
format Article
sources DOAJ
author Ebtisam A. Aldaais
spellingShingle Ebtisam A. Aldaais
New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers
Results in Materials
Thermotropic polymers
Decoupled SCF theory
Polymer physics
author_facet Ebtisam A. Aldaais
author_sort Ebtisam A. Aldaais
title New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers
title_short New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers
title_full New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers
title_fullStr New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers
title_full_unstemmed New method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers
title_sort new method of increased accuracy for the calculation of intermolecular interactions in thermotropic polymers
publisher Elsevier
series Results in Materials
issn 2590-048X
publishDate 2019-08-01
description Thermotropic polymeric tissues have attracted considerable scientific interest for their useful biomedical applications. The complex coupling of van der Waals and steric interactions influences the thermal response of polymers’ molecular structure. Comprehensive theories that govern the molecular reorganization define the intramolecular interactions as the interactions between segments of the same polymer, and intermolecular interactions as the interactions between different polymers' segments of differ. The attractive interactions between polymer segments are determined via exact calculations of the intramolecular interactions, while the intermolecular interactions are treated with a self-consistent approximation, which leads to the double counting of the intermolecular interactions. Our decoupled self-consistent field theory (SCF) corrects for that double counting. The results show that the decoupled SCF theory considers less attractive energy than the standard one. These results improve the calculations of several parameters, such as the polymers end-to-end distance, and distinguish the critical parameters that lead to the formation of micelles.
topic Thermotropic polymers
Decoupled SCF theory
Polymer physics
url http://www.sciencedirect.com/science/article/pii/S2590048X19300135
work_keys_str_mv AT ebtisamaaldaais newmethodofincreasedaccuracyforthecalculationofintermolecularinteractionsinthermotropicpolymers
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