Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)

Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)

The PtII ion in the title complex, [PtBr2(C10H9N3)], is four-coordinated in an essentially square-planar environment by two N atoms from a chelating di-2-pyridylamine (dpa) ligand and two Br− anions. The dpa ligand is not planar, with the dihedral angle between the pyridine rings being...

Full description

Bibliographic Details
Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812011300
id doaj-b968b7b9a5174f82a3680fcefb1da6e9
record_format Article
spelling doaj-b968b7b9a5174f82a3680fcefb1da6e92020-11-24T21:50:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m453m45310.1107/S1600536812011300Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)Kwang HaThe PtII ion in the title complex, [PtBr2(C10H9N3)], is four-coordinated in an essentially square-planar environment by two N atoms from a chelating di-2-pyridylamine (dpa) ligand and two Br− anions. The dpa ligand is not planar, with the dihedral angle between the pyridine rings being 40.8 (2)°. The complex molecules are stacked in columns along [001] through π–π interactions between the pyridine rings [centroid–centroid distances = 3.437 (3) and 3.520 (3) Å]. Intermolecular N—H...Br hydrogen bonds connect the molecules into chains running along [010]. Intramolecular C—H...Br interactions are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812011300
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)
Acta Crystallographica Section E
author_facet Kwang Ha
author_sort Kwang Ha
title Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)
title_short Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)
title_full Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)
title_fullStr Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)
title_full_unstemmed Dibromido(di-2-pyridylamine-κ2N2,N2′)platinum(II)
title_sort dibromido(di-2-pyridylamine-κ2n2,n2′)platinum(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description The PtII ion in the title complex, [PtBr2(C10H9N3)], is four-coordinated in an essentially square-planar environment by two N atoms from a chelating di-2-pyridylamine (dpa) ligand and two Br− anions. The dpa ligand is not planar, with the dihedral angle between the pyridine rings being 40.8 (2)°. The complex molecules are stacked in columns along [001] through π–π interactions between the pyridine rings [centroid–centroid distances = 3.437 (3) and 3.520 (3) Å]. Intermolecular N—H...Br hydrogen bonds connect the molecules into chains running along [010]. Intramolecular C—H...Br interactions are also observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812011300
work_keys_str_mv AT kwangha dibromidodi2pyridylamineamp9542n2n2amp8242platinumii
_version_ 1725881347156738048

Similar Items