Hexakis(1H-imidazole-κN3)nickel(II) bis(3-thienylacetate)
In the title complex, [Ni(C3H4N2)6](C6H5O2S)2, the NiII atom displays an octahedral coordination geometry, defined by six N atoms from the imidazole ligands. Intermolecular N—H...O hydrogen-bonding interactions between the cationic complex and 3-thienylacetate anions form a three-dimension...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808006363 |
| Summary: | In the title complex, [Ni(C3H4N2)6](C6H5O2S)2, the NiII atom displays an octahedral coordination geometry, defined by six N atoms from the imidazole ligands. Intermolecular N—H...O hydrogen-bonding interactions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5). |
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| ISSN: | 1600-5368 |