Direct evidence for hula twist and single-bond rotation photoproducts

Photoisomerization mechanisms govern important (bio)catalytic reactions and lie at the core of many functional materials. Here, the authors report a molecular setup that allows for the direct and separate observation of three fundamental photoreactions, namely the hula twist, single-bond rotation, a...

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Main Authors: Aaron Gerwien, Monika Schildhauer, Stefan Thumser, Peter Mayer, Henry Dube
Format: Article
Language:English
Published: Nature Publishing Group 2018-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-04928-9
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spelling doaj-b8cbd894250843fbbc3eb2daaf3d49312021-05-11T09:44:45ZengNature Publishing GroupNature Communications2041-17232018-06-01911910.1038/s41467-018-04928-9Direct evidence for hula twist and single-bond rotation photoproductsAaron Gerwien0Monika Schildhauer1Stefan Thumser2Peter Mayer3Henry Dube4Department of Chemistry, Ludwig-Maximilians-Universität München and Munich Center for Integrated Protein Science CIPSMDepartment of Chemistry, Ludwig-Maximilians-Universität München and Munich Center for Integrated Protein Science CIPSMDepartment of Chemistry, Ludwig-Maximilians-Universität München and Munich Center for Integrated Protein Science CIPSMDepartment of Chemistry, Ludwig-Maximilians-Universität München and Munich Center for Integrated Protein Science CIPSMDepartment of Chemistry, Ludwig-Maximilians-Universität München and Munich Center for Integrated Protein Science CIPSMPhotoisomerization mechanisms govern important (bio)catalytic reactions and lie at the core of many functional materials. Here, the authors report a molecular setup that allows for the direct and separate observation of three fundamental photoreactions, namely the hula twist, single-bond rotation, as well as double-bond isomerization.https://doi.org/10.1038/s41467-018-04928-9
collection DOAJ
language English
format Article
sources DOAJ
author Aaron Gerwien
Monika Schildhauer
Stefan Thumser
Peter Mayer
Henry Dube
spellingShingle Aaron Gerwien
Monika Schildhauer
Stefan Thumser
Peter Mayer
Henry Dube
Direct evidence for hula twist and single-bond rotation photoproducts
Nature Communications
author_facet Aaron Gerwien
Monika Schildhauer
Stefan Thumser
Peter Mayer
Henry Dube
author_sort Aaron Gerwien
title Direct evidence for hula twist and single-bond rotation photoproducts
title_short Direct evidence for hula twist and single-bond rotation photoproducts
title_full Direct evidence for hula twist and single-bond rotation photoproducts
title_fullStr Direct evidence for hula twist and single-bond rotation photoproducts
title_full_unstemmed Direct evidence for hula twist and single-bond rotation photoproducts
title_sort direct evidence for hula twist and single-bond rotation photoproducts
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2018-06-01
description Photoisomerization mechanisms govern important (bio)catalytic reactions and lie at the core of many functional materials. Here, the authors report a molecular setup that allows for the direct and separate observation of three fundamental photoreactions, namely the hula twist, single-bond rotation, as well as double-bond isomerization.
url https://doi.org/10.1038/s41467-018-04928-9
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