Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]

Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]

The molecule of the title compound, [Ti2(CH3)2(CH3O)2(C11H15O)4] or {[Ti(Me)(μ-OCH3)(OC6H3CMe3-2-Me-6)]2}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two TiIV atoms [T...

Full description

Bibliographic Details
Main Authors: Alastair J. Nielson, Chaohong Shen, Joyce M. Waters
Format: Article
Language:English
Published: International Union of Crystallography 2013-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813025634
id doaj-b84e5d4e859b4cfb9c6802d93b5a0de4
record_format Article
spelling doaj-b84e5d4e859b4cfb9c6802d93b5a0de42020-11-24T22:15:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-10-016910m554m55510.1107/S1600536813025634Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]Alastair J. NielsonChaohong ShenJoyce M. WatersThe molecule of the title compound, [Ti2(CH3)2(CH3O)2(C11H15O)4] or {[Ti(Me)(μ-OCH3)(OC6H3CMe3-2-Me-6)]2}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two TiIV atoms [Ti—O bond lengths of 1.9794 (12) and 2.0603 (12) Å] with the two phenolato ligands occupying the remaining basal sites [Ti—O 1.8218 (11) and 1.8135 (11) Å]. The Ti—O—C phenolato bond angles are similar at 161.24 (10) and 160.66 (11)°. The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536813025634
collection DOAJ
language English
format Article
sources DOAJ
author Alastair J. Nielson
Chaohong Shen
Joyce M. Waters
spellingShingle Alastair J. Nielson
Chaohong Shen
Joyce M. Waters
Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]
Acta Crystallographica Section E
author_facet Alastair J. Nielson
Chaohong Shen
Joyce M. Waters
author_sort Alastair J. Nielson
title Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]
title_short Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]
title_full Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]
title_fullStr Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]
title_full_unstemmed Di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κO)methyltitanium(IV)]
title_sort di-μ-methanolato-bis[(2-tert-butyl-6-methylphenolato-κo)methyltitanium(iv)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-10-01
description The molecule of the title compound, [Ti2(CH3)2(CH3O)2(C11H15O)4] or {[Ti(Me)(μ-OCH3)(OC6H3CMe3-2-Me-6)]2}, has a centrosymmetric, dimeric structure with a distorted square pyramidal array about each titanium atom. The methoxide ligands form an asymmetric bridge between the two TiIV atoms [Ti—O bond lengths of 1.9794 (12) and 2.0603 (12) Å] with the two phenolato ligands occupying the remaining basal sites [Ti—O 1.8218 (11) and 1.8135 (11) Å]. The Ti—O—C phenolato bond angles are similar at 161.24 (10) and 160.66 (11)°. The methyl ligand attached to the metal atom has a Ti—C bond length of 2.0878 (17) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813025634
work_keys_str_mv AT alastairjnielson di956methanolatobis2tertbutyl6methylphenolato954omethyltitaniumiv
AT chaohongshen di956methanolatobis2tertbutyl6methylphenolato954omethyltitaniumiv
AT joycemwaters di956methanolatobis2tertbutyl6methylphenolato954omethyltitaniumiv
_version_ 1725796640033341440

Similar Items