Kinetics and Mechanism of the Oxidation of Lactic Acid and Mandelic Acid by Pyridinium Chlorochromate in Aqueous Acidic Medium

Kinetics and Mechanism of the Oxidation of Lactic Acid and Mandelic Acid by Pyridinium Chlorochromate in Aqueous Acidic Medium

Pyridinium chlorochromate (PCC) act as two electron oxidant in kinetic studies of the oxidation of lactic and mandelic acid in acidic medium. The influence of several factors such as acidity, salts, solvent composition and temperature on the reaction rate has been studied. The reaction shows first o...

Full description

Bibliographic Details
Main Authors:	Sapana Jain, B. L. Hiran, C. V. Bhatt
Format:	Article
Language:	English
Published:	Hindawi Limited 2009-01-01
Series:	E-Journal of Chemistry
Online Access:	http://dx.doi.org/10.1155/2009/786890

Similar Items

Oxidation of Some Aliphatic Alcohols by Pyridinium Chlorochromate -Kinetics and Mechanism
by: Sapana Jain, et al.
Published: (2009-01-01)

Oxidation of phenyl alanine by pyridinium chlorochromate in acidic DMF–water medium: A kinetic study
by: B.L. Hiran, et al.
Published: (2016-11-01)

Kinetics and mechanism of the oxidation of some substituted aldonitrones by quinolinium chlorochromate in aqueous DMF medium in the absence and presence of oxalic acid
by: Rajarajan Govindasamy, et al.
Published: (2009-01-01)

Kinetics and mechanism of the oxidation of some substituted aldonitrones by quinolinium chlorochromate in aqueous DMF medium in the absence and presence of oxalic acid
by: GOVINDASAMY RAJARAJAN, et al.
Published: (2009-02-01)

The Kinetics of Tripropylammonium Fluorochromate Oxidation of Mandelic Acids
by: Shanmugam Shanthi, et al.
Published: (2018-06-01)

Pyridinium chlorochromate chemistry. New insight into oxidation of tetrahydrofurans
by: Sabrina Zaccaria, et al.
Published: (2017-05-01)

Oxidation of Chalcones by Morpholinium Chlorochromate with Oxalic Acid as Catalyst: Kinetic and Mechanistic Study
by: K. Rajalakshmi, et al.
Published: (2013-01-01)

Study of the kinetic behavior of mandelic acid oxidation by vanadium(V) in sulfuric acid medium: effect of CTAB presence
by: Rômulo Augusto Ando, et al.
Published: (2006-02-01)

Oxidation of aliphatic alcohols by triethylammonium chlorochromate in non-aqueous medium – A kinetic and mechanistic study
by: S. Sheik Mansoor, et al.
Published: (2014-07-01)

Kinetics and mechanism of the oxidation of methionine by quinolinium chlorochromate
by: Pandeeswaran M., et al.
Published: (2005-01-01)

Kinetics and mechanism of the oxidation of methionine by quinolinium chlorochromate
by: K. P. ELANGO, et al.
Published: (2005-02-01)

Kinetics and Mechanism of Oxidation of Glutamic Acid by N-Bromophthalimide in Aqueous Acidic Medium
by: N. M. I. Alhaji, et al.
Published: (2011-01-01)

Study of poly (vinyl pyridinium chlorochromate) and poly (vinyl pyridinium dichromate) as polymer reagents
by: ZHAN,YA-LING, et al.
Published: (1990)

The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media
by: Jeyanthi Fatima G., et al.
Published: (2002-01-01)

Oxidation of methionine by tetraethylammonium chlorochromate in non-aqueous media – A kinetic and mechanistic study
by: S. Sheik Mansoor, et al.
Published: (2015-07-01)

The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media
by: G. FATIMA JEYANTHI, et al.
Published: (2002-12-01)

Kinetics and Mechanism of Oxidation of Isoleucine by N-Bromophthalimide in Aqueous Perchloric Acid Medium
by: N. M. I. Alhaji, et al.
Published: (2011-01-01)

Kinetics of Oxidation of 3-Benzoylpropionic Acid by N-Chlorobenzamide in Aqueous Acetic Acid Medium
by: N. A. Mohamed Farook, et al.
Published: (2011-01-01)

Kinetics of Oxidation of 3-Benzoylpropionic Acid by N-Bromoacetamide in Aqueous Acetic Acid Medium
by: N. A. Mohamed Farook, et al.
Published: (2011-01-01)

Kinetics of Oxidation of Some Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium
by: N. A. Mohamed Farook, et al.
Published: (2004-01-01)

Kinetics and Mechanism of Oxidation of Aromatic Aldehydes by Imidazolium Dichromate in Aqueous Acetic Acid Medium
by: S. Sheik Mansoor, et al.
Published: (2009-01-01)

Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium
by: N. A. Mohamed Farook, et al.
Published: (2004-01-01)

Assessment of Antioxidant, Whitening and Antibacterial Capabilities Between L-Mandelic and D-Mandelic Acids
by: Chiang Pei Fang, et al.
Published: (2014)

The electrochemical oxidation of various substituted mandelic acids: an electrochemical and product analysis study
by: Claeys, Maurice Roger.
Published: (2015)

OXIDATION OF BENZYLIC SECONDARY ALCOHOL WITH PYRIDINIUM CHLOROCHROMATE-ALUMINA (PCC-Al<sub>2</sub>O<sub>3</sub>)
by: Hanoch J. Sohilait
Published: (2010-06-01)

Kinetics and Mechanism of Oxidation of Diethyl Ether by Chloramine-T in Acidic Medium
by: Y. I. Hassan, et al.
Published: (2012-01-01)

Weak Interactions in Cocrystals of Isoniazid with Glycolic and Mandelic Acids
by: Raquel Álvarez-Vidaurre, et al.
Published: (2021-03-01)

Kinetic Studies on the Oxidation of Some para and meta-Substituted Cinnamic Acids by Pyridinium Bromochromate in the Presence of Oxalic Acid (A Co-oxidation Study)
by: G. Vanangamudi, et al.
Published: (2009-01-01)

Preliminary Study on the Kinetics and Mechanism of the Oxidation of Naphthol Green B by Dichromate Ion in Aqueous Hydrochloric Acid Medium
by: Bako Myek, et al.
Published: (2014-04-01)

Guanidinium chlorochromate
by: Hoong-Kun Fun, et al.
Published: (2010-02-01)

Kinetic Study of the Ce(III)- or Mn(II)- catalyzed Bromate- Mandelic acid-Ketone Oscillating Reaction
by: Shwn-Shiow Lee, et al.

Oxidation of 3,4,5-trimethoxybenzaldehyde by pyridinium fluorochromate in N,N-dimethyl formamide medium: A kinetic and mechanistic study
by: Basanti Lal Hiran, et al.
Published: (2016-09-01)

Crystallographic studies related to the use of mandelic acid and camphor-10-sulphonic acid as resolving agents
by: Armstrong, Susan
Published: (1991)

The acidity of substituted pyridinium ions in methanol
by: Waters, J. A.
Published: (1980)

Quinaldinium Chlorochromate(VI), (QnCC) Catalyzed Oxidation of Alcohols with Periodic Acid Under Solvent-Free Conditions and Microwave Irradition
by: Melek Canbulat Özdemir
Published: (2018-01-01)

Study of the kinetics and mechanism of oxidation of some esters by potassium permanganate in acid medium
by: Ibrahim Younis Mohammad
Published: (2013-06-01)

Kinetic Study on Induced Electron Transfer Reaction in Pentaamminecobalt(III) Complexes of α-Hydroxy Acids by Pyridinium Fluorochromate in Micellar Medium
by: B. Mohammed Nawaz, et al.
Published: (2011-01-01)

Determination of the interfacial energy of mandelic acid from the induction time data
by: Szu Chia Chiu, et al.
Published: (2016)

Chiral separations of mandelic acid by HPLC using molecularly imprinted polymers
by: Chin-Yin Hung, et al.
Published: (2018-05-01)

Resolution of Halogenated Mandelic Acids through Enantiospecific Co-Crystallization with Levetiracetam
by: Jie Wang, et al.
Published: (2021-09-01)