Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties

Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties

Summary: In the latest decade, two-dimensional (2D) π-d conjugated metal organic frameworks (MOFs) constructed from metal ions with square-planar coordination geometry and benzene- or triphenylene-derived ligands with ortho-disubstituted N, O, or S donor atoms have received great research interests...

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Main Authors: Yutao Cui, Jie Yan, Zhijun Chen, Weilong Xing, Chunhui Ye, Xiang Li, Ye Zou, Yimeng Sun, Caiming Liu, Wei Xu, Daoben Zhu
Format: Article
Language:English
Published: Elsevier 2020-01-01
Series:iScience
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004219305589
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spelling doaj-b81713cc2421496ebdf22e996a8fca1d2020-11-25T01:54:35ZengElsevieriScience2589-00422020-01-01231Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic PropertiesYutao Cui0Jie Yan1Zhijun Chen2Weilong Xing3Chunhui Ye4Xiang Li5Ye Zou6Yimeng Sun7Caiming Liu8Wei Xu9Daoben Zhu10Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, ChinaBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, ChinaBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, ChinaBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, ChinaBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, ChinaInstitute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, ChinaBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, China; Corresponding authorBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, China; Corresponding authorBeijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, ChinaSummary: In the latest decade, two-dimensional (2D) π-d conjugated metal organic frameworks (MOFs) constructed from metal ions with square-planar coordination geometry and benzene- or triphenylene-derived ligands with ortho-disubstituted N, O, or S donor atoms have received great research interests because of their exceptional physical properties and promising applications. New MOFs of this class are constantly being reported, but 2D metal bis(diselenolene) MOFs based on organic ligands with ortho-disubstituted Se donor atoms have not been synthesized. Herein, a Lewis-acid-induced dealkylation protocol is introduced to the synthesis of arenepolyselenols and related coordination polymers. A triphenylene-derived diselenaborole compound is synthesized and employed as precursor reagent for the synthesis of 2,3,6,7,10,11-triphenylenehexaselenol (H6TPHS) and the first conductive metal organic framework namely Co-TPHS based on triphenylenehexaselenolate (TPHS6−). Co-TPHS exhibits porous honeycomb 2D structure and electrically conductive and glassy magnetic properties. : Subject Areas: Chemical Synthesis; Magnetic Property; Polymers Subject Areas: Chemical Synthesis, Magnetic Property, Polymershttp://www.sciencedirect.com/science/article/pii/S2589004219305589
collection DOAJ
language English
format Article
sources DOAJ
author Yutao Cui
Jie Yan
Zhijun Chen
Weilong Xing
Chunhui Ye
Xiang Li
Ye Zou
Yimeng Sun
Caiming Liu
Wei Xu
Daoben Zhu
spellingShingle Yutao Cui
Jie Yan
Zhijun Chen
Weilong Xing
Chunhui Ye
Xiang Li
Ye Zou
Yimeng Sun
Caiming Liu
Wei Xu
Daoben Zhu
Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties
iScience
author_facet Yutao Cui
Jie Yan
Zhijun Chen
Weilong Xing
Chunhui Ye
Xiang Li
Ye Zou
Yimeng Sun
Caiming Liu
Wei Xu
Daoben Zhu
author_sort Yutao Cui
title Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties
title_short Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties
title_full Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties
title_fullStr Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties
title_full_unstemmed Synthetic Route to a Triphenylenehexaselenol-Based Metal Organic Framework with Semi-conductive and Glassy Magnetic Properties
title_sort synthetic route to a triphenylenehexaselenol-based metal organic framework with semi-conductive and glassy magnetic properties
publisher Elsevier
series iScience
issn 2589-0042
publishDate 2020-01-01
description Summary: In the latest decade, two-dimensional (2D) π-d conjugated metal organic frameworks (MOFs) constructed from metal ions with square-planar coordination geometry and benzene- or triphenylene-derived ligands with ortho-disubstituted N, O, or S donor atoms have received great research interests because of their exceptional physical properties and promising applications. New MOFs of this class are constantly being reported, but 2D metal bis(diselenolene) MOFs based on organic ligands with ortho-disubstituted Se donor atoms have not been synthesized. Herein, a Lewis-acid-induced dealkylation protocol is introduced to the synthesis of arenepolyselenols and related coordination polymers. A triphenylene-derived diselenaborole compound is synthesized and employed as precursor reagent for the synthesis of 2,3,6,7,10,11-triphenylenehexaselenol (H6TPHS) and the first conductive metal organic framework namely Co-TPHS based on triphenylenehexaselenolate (TPHS6−). Co-TPHS exhibits porous honeycomb 2D structure and electrically conductive and glassy magnetic properties. : Subject Areas: Chemical Synthesis; Magnetic Property; Polymers Subject Areas: Chemical Synthesis, Magnetic Property, Polymers
url http://www.sciencedirect.com/science/article/pii/S2589004219305589
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