EPOXIDATION OF ALLYL ALCOHOL TO GLYCIDOL WITH HYDROGEN PEROXIDE AT TITANIUM SILICALITE

EPOXIDATION OF ALLYL ALCOHOL TO GLYCIDOL WITH HYDROGEN PEROXIDE AT TITANIUM SILICALITE

It was studied the epoxidation mechanism of allyl alcohol using titanosilicate zeolite (TS-1) at 40°C by means of procedures for the nomination and discrimination of mechanism hypotheses. The hypotheses was carried out using the literature data and the preliminary experiment results. Discrimination...

Full description

Bibliographic Details
Main Authors:	Zh. Yu. Pastukhova, F. D. Nasybulin, A. V. Sulimov, V. R. Flid, L. G. Bruk
Format:	Article
Language:	Russian
Published:	MIREA - Russian Technological University 2016-08-01
Series:	Тонкие химические технологии
Subjects:	kinetics mechanism epoxidation hydrogen peroxide allyl alcohol glycidol catalysis catalyst ts-1
Online Access:	https://www.finechem-mirea.ru/jour/article/view/36

Similar Items

LOW-WASTE TECHNOLOGY OF GLYCIDOL PRODUCTION BY PEROXIDE METHOD
by: S. V. Leont'eva, et al.
Published: (2018-06-01)

The utilization of the mesoporous Ti-SBA-15 catalyst in the epoxidation of allyl alcohol to glycidol and diglycidyl ether in the water medium
by: Wróblewska Agnieszka, et al.
Published: (2015-12-01)

Bio-Glycidol Conversion to Solketal over Acid Heterogeneous Catalysts: Synthesis and Theoretical Approach
by: Maria Ricciardi, et al.
Published: (2018-09-01)

Epoxidation of allyl-glycidyl ether with hydrogen peroxide over Ti-SBA-15 catalyst and in methanol medium
by: Walasek Marika, et al.
Published: (2016-12-01)

Synthesis of Low Cost Titanium Silicalite-1 Zeolite for Highly Efficient Propylene Epoxidation
by: Meng Liu, et al.
Published: (2021-06-01)

Optimization of the Synthesis of Glycerol Derived Monoethers from Glycidol by Means of Heterogeneous Acid Catalysis
by: Elisabet Pires, et al.
Published: (2018-11-01)

Synthesis of allyl-glycidyl ether by the epoxidation of diallyl ether with t-butyl hydroperoxide over the Ti-MWW catalyst
by: Agnieszka Wróblewska, et al.
Published: (2017-01-01)

Boron removal from water and wastewater using new polystyrene-based resin grafted with glycidol
by: Joanna Kluczka, et al.
Published: (2015-09-01)

Thiol-ene Cross-linked Poly(glycidol) / Hyaluronic Acid Based Hydrogels for 3D Bioprinting
by: Schäfer [geb. Stichler], Simone
Published: (2019)

Synthesis and Reactivity of Allylic Amines in Palladium Catalysis
by: Dubovyk, Igor
Published: (2012)

Synthesis and Reactivity of Allylic Amines in Palladium Catalysis
by: Dubovyk, Igor
Published: (2012)

The Epoxidation of Limonene over the TS-1 and Ti-SBA-15 Catalysts
by: Agnieszka Wróblewska
Published: (2014-11-01)

Does External Exposure of Glycidol-Related Chemicals Influence the Forming of the Hemoglobin Adduct, <i>N</i>-(2,3-dihydroxypropyl)valine, as a Biomarker of Internal Exposure to Glycidol?
by: Yuko Shimamura, et al.
Published: (2020-12-01)

Indium-mediated allylation in carbohydrate synthesis: A short and efficient approach towards higher 2-acetamido-2-deoxy sugars
by: Christopher Albler, et al.
Published: (2014-09-01)

Development of New Chiral Bicyclic Ligands : Applications in Catalytic Asymmetric Transfer Hydrogenation, Epoxidations, and Epoxide Rearrangements
by: Gayet, Arnaud
Published: (2005)

Internal Doses of Glycidol in Children and Estimation of Associated Cancer Risk
by: Jenny Aasa, et al.
Published: (2019-02-01)

The tandem catalytic asymmetric allene diboration/imine allylation and the asymmetric transition-metal-catalyzed conjugate allylation of activated enones
by: Sieber, Joshua Daniel
Published: (2008)

A Highly Diastereoselective and Enantioselective Phase-Transfer Catalyzed Epoxidation of β-Trifluoromethyl-β,β-disubstituted Enones with H2O2
by: Shaoxiang Wu, et al.
Published: (2015-12-01)

Ativação do peróxido de hidrogênio para a epoxidação de olefinas não-funcionalizadas Activating agents of the hydrogen peroxide in the epoxidation of unfunctionalized alkenes
by: Maria Luiza Ambros von Holleben, et al.
Published: (1997-02-01)

New Molybdenum(II) Complexes with α-Diimine Ligands: Synthesis, Structure, and Catalytic Activity in Olefin Epoxidation
by: Maria Vasconcellos-Dias, et al.
Published: (2019-02-01)

(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
by: Francesco Paolo Ballistreri, et al.
Published: (2016-07-01)

A Study of Allylic Aminations as Catalyzed by Heterobimetallic Pd-Ti Complexes
by: Ellis, Diana Lauren
Published: (2015)

Switching off H2O2 Decomposition during TS-1 Catalysed Epoxidation via Post-Synthetic Active Site Modification
by: Ceri Hammond, et al.
Published: (2015-12-01)

Chiral Recognition of Homochiral Poly (amidoamine) Dendrimers Substituted with <i>R</i>- and <i>S</i>-Glycidol by Keratinocyte (HaCaT) and Squamous Carcinoma (SCC-15) Cells In Vitro
by: Małgorzata Malinga-Drozd, et al.
Published: (2021-03-01)

Allylic amination and carbon–carbon double bond transposition catalyzed by cobalt(II) azodioxide complexes
by: Kylin A. Emhoff, et al.
Published: (2020-01-01)

Allylic Alkylations Catalyzed By Palladium-Bis(oxazoline) Complexes Derived From Heteroarylidene Malonate Derivatives
by: Bin Fu, et al.
Published: (2012-02-01)

Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine
by: Vladislav V. Fomenko, et al.
Published: (2021-03-01)

Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective
by: Casper Junker Engelin, et al.
Published: (2011-01-01)

Catalytic Enantioselective Allylation of Imines and Trifluoroketones Using New and Underutilized Organoboron Reagents
by: Mszar, Nicholas Walter
Published: (2017)

Isotherms, kinetics, and thermodynamics of boron adsorption on fibrous polymeric chelator containing glycidol moiety optimized with response surface method
by: Haruna Kolawole Afolabi, et al.
Published: (2021-12-01)

Recent Advances in the Application of Chiral Phosphine Ligands in Pd-Catalysed Asymmetric Allylic Alkylation
by: Erika Martin, et al.
Published: (2011-01-01)

Accessing Chemically Differentiated 1,5-dienes Through Palladium Catalyzed Allyl-Allyl Cross-Coupling with Internal Allyl Electrophiles
by: Batten, Amanda Lynn
Published: (2015)

Soybean Oil Epoxidation: Kinetics of the Epoxide Ring Opening Reactions
by: Elio Santacesaria, et al.
Published: (2020-09-01)

Gold(I)-Catalyzed Dehydrative Amination and Etherification of Allylic Alcohols
by: Mukherjee, Paramita
Published: (2012)

Technological Parameters of Epoxidation of Sesame Oil with Performic Acid
by: Musik Marlena, et al.
Published: (2018-09-01)

Transition metal-catalyzed allylic and vinylic functionalization : Method development and mechanistic investigations
by: Larsson, Johanna M.
Published: (2013)

Platinum-Catalyzed Allylation of 2,3-Disubstituted Indoles with Allylic Acetates
by: Bai-Jing Peng, et al.
Published: (2017-11-01)

Gold(I)-catalysed one-pot synthesis of chromans using allylic alcohols and phenols
by: Eloi Coutant, et al.
Published: (2013-09-01)

Epoxidation of Karanja (<i>Millettia pinnata</i>) Oil Methyl Esters in the Presence of Hydrogen Peroxide over a Simple Niobium-Containing Catalyst
by: Nicola Scotti, et al.
Published: (2019-04-01)

Stereodivergent Pd/Cu Catalysis for Asymmetric Desymmetric Alkylation of Allylic Geminal Dicarboxylates
by: Gridneva, T., et al.
Published: (2022)