7-Chloro-4-[(E)-2-(2,5-dimethoxybenzylidene)hydrazin-1-yl]quinoline

In the nearly planar title compound (r.m.s. deviation for the 24 non-H atoms = 0.064 Å), C18H16ClN3O2, the conformation about the N=C bond is E. Supramolecular chains propagated by glide symmetry along [001] are found in the crystal packing. These are sustained by N&am...

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Bibliographic Details
Main Authors: Marcus V. N. de Souza, Marcelle de Lima Ferreira, Solange M. S. V. Wardell, Edward R. T. Tiekink, James L. Wardell
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812012871
Description
Summary:In the nearly planar title compound (r.m.s. deviation for the 24 non-H atoms = 0.064 Å), C18H16ClN3O2, the conformation about the N=C bond is E. Supramolecular chains propagated by glide symmetry along [001] are found in the crystal packing. These are sustained by N—H...N hydrogen bonds with the quinoline N atom being the acceptor. The chains are connected into a three-dimensional architecture by π–π interactions involving all three aromatic rings [centroid–centroid distances = 3.5650 (9)–3.6264 (9) Å].
ISSN:1600-5368