Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends

Terpenic olefins constitute a relevant platform of renewable molecules, which could be used as key intermediates for the perfumery, flavoring, and pharmaceutical industries. The upgrading of these cheap and available agro-resources through catalytic oxidation processes remains of great interest, lea...

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Main Authors:	Audrey Denicourt-Nowicki, Mariem Rauchdi, Mustapha Ait Ali, Alain Roucoux
Format:	Article
Language:	English
Published:	MDPI AG 2019-10-01
Series:	Catalysts
Subjects:	terpenes catalysts epoxidation allylic oxidation sustainable chemistry
Online Access:	https://www.mdpi.com/2073-4344/9/11/893

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spelling	doaj-b790b7993f6b4064b1cfa940e66ac9362020-11-25T01:12:24ZengMDPI AGCatalysts2073-43442019-10-0191189310.3390/catal9110893catal9110893Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future TrendsAudrey Denicourt-Nowicki0Mariem Rauchdi1Mustapha Ait Ali2Alain Roucoux3Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR-UMR 6226, F-35000 Rennes, FranceEcole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR-UMR 6226, F-35000 Rennes, FranceEquipe de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, Université Cadi Ayyad, BP 2390 Marrakech, MoroccoEcole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR-UMR 6226, F-35000 Rennes, FranceTerpenic olefins constitute a relevant platform of renewable molecules, which could be used as key intermediates for the perfumery, flavoring, and pharmaceutical industries. The upgrading of these cheap and available agro-resources through catalytic oxidation processes remains of great interest, leading to the formation of either epoxides via the oxidation of the olefinic bond or α,β-unsaturated ketones by the Csp<sup>3</sup>-H functionalization at the α-position of the double bond. This critical review summarizes some of the most relevant homogeneous or heterogeneous catalysts designed for the oxidation of some abundant terpenic olefins in the last decade (2008−2018).https://www.mdpi.com/2073-4344/9/11/893terpenescatalystsepoxidationallylic oxidationsustainable chemistry
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Audrey Denicourt-Nowicki Mariem Rauchdi Mustapha Ait Ali Alain Roucoux
spellingShingle	Audrey Denicourt-Nowicki Mariem Rauchdi Mustapha Ait Ali Alain Roucoux Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends Catalysts terpenes catalysts epoxidation allylic oxidation sustainable chemistry
author_facet	Audrey Denicourt-Nowicki Mariem Rauchdi Mustapha Ait Ali Alain Roucoux
author_sort	Audrey Denicourt-Nowicki
title	Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends
title_short	Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends
title_full	Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends
title_fullStr	Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends
title_full_unstemmed	Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends
title_sort	catalytic oxidation processes for the upgrading of terpenes: state-of-the-art and future trends
publisher	MDPI AG
series	Catalysts
issn	2073-4344
publishDate	2019-10-01
description	Terpenic olefins constitute a relevant platform of renewable molecules, which could be used as key intermediates for the perfumery, flavoring, and pharmaceutical industries. The upgrading of these cheap and available agro-resources through catalytic oxidation processes remains of great interest, leading to the formation of either epoxides via the oxidation of the olefinic bond or α,β-unsaturated ketones by the Csp<sup>3</sup>-H functionalization at the α-position of the double bond. This critical review summarizes some of the most relevant homogeneous or heterogeneous catalysts designed for the oxidation of some abundant terpenic olefins in the last decade (2008−2018).
topic	terpenes catalysts epoxidation allylic oxidation sustainable chemistry
url	https://www.mdpi.com/2073-4344/9/11/893
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Catalytic Oxidation Processes for the Upgrading of Terpenes: State-of-the-Art and Future Trends

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