Visible Light-Induced Reactivity of Plasmonic Gold Nanoparticles Incorporated into TiO₂ Matrix towards 2-Chloroethyl Ethyl Sulfide

• Main Authors: Wesley Gordon, Alex Balboa, Spencer Giles, Albert Epshteyn, Oscar Ávalos-Ovando, Alexander Govorov, Monica McEntee, Olga Baturina
• Format: Article
• Language: English
• Published: MDPI AG 2021-06-01
• Series: Crystals
• Subjects: plasmonic gold nanoparticles; 2-chloroethyl ethyl sulfide; photocatalysis; in situ DRIFTS
• Online Access: https://www.mdpi.com/2073-4352/11/6/659
• ISSN: 2073-4352

Inexpensive strategies for efficient decontamination of hazardous chemicals are required. In this study, the effect of visible light (λ > 400 nm) on the decomposition of 2-chloroethyl ethyl sulfide (2-CEES, a sulfur mustard (HD) simulant) on Au/TiO₂ photocatalyst under anaerobic and aerobic conditions has been investigated in situ by diffuse reflectance infrared Fourier –transformed spectroscopy (DRIFTS). Under anaerobic conditions, 2-CEES partially desorbs from the Au/TiO₂ surface likely due to the photothermal effect, induced by photo-excited plasmonic Au nanoparticles. In the aerobic experiment, no visible light effect is observed. We attribute this behavior to 2-CEES consumption by hydrolysis to 2-ethylthio ethanol in the dark, prior to visible light excitation. Oxygen activates water molecules in the dark, resulting in accelerated 2-CEES hydrolysis.