Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes

The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of...

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Main Authors:	Yali Zhou, Xingjun Xu, Hongwei Sun, Guanyu Tao, Xiao-Yong Chang, Xiangyou Xing, Bo Chen, Chen Xu
Format:	Article
Language:	English
Published:	Nature Publishing Group 2021-03-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-021-22287-w

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spelling	doaj-b7558009dee04f8caca8209b803af4dc2021-04-04T11:12:52ZengNature Publishing GroupNature Communications2041-17232021-03-0112111110.1038/s41467-021-22287-wDevelopment of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenesYali Zhou0Xingjun Xu1Hongwei Sun2Guanyu Tao3Xiao-Yong Chang4Xiangyou Xing5Bo Chen6Chen Xu7Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyAcademy for Advanced Interdisciplinary Studies, Southern University of Science and TechnologyShenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and TechnologyThe direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions.https://doi.org/10.1038/s41467-021-22287-w
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Yali Zhou Xingjun Xu Hongwei Sun Guanyu Tao Xiao-Yong Chang Xiangyou Xing Bo Chen Chen Xu
spellingShingle	Yali Zhou Xingjun Xu Hongwei Sun Guanyu Tao Xiao-Yong Chang Xiangyou Xing Bo Chen Chen Xu Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes Nature Communications
author_facet	Yali Zhou Xingjun Xu Hongwei Sun Guanyu Tao Xiao-Yong Chang Xiangyou Xing Bo Chen Chen Xu
author_sort	Yali Zhou
title	Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_short	Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_full	Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_fullStr	Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_full_unstemmed	Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
title_sort	development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2021-03-01
description	The direct addition of an O–H (hydroalkoxylation) or an N–H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report “donor–acceptor”-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions.
url	https://doi.org/10.1038/s41467-021-22287-w
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Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes

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