Elution of Monomers from Provisional Composite Materials

The aim of this study was to evaluate the elution of substances from different materials used for the manufacturing of temporary indirect restorations, after storage in saliva and ethanol 75%. 10 samples of three chemically cured materials (Protemp 3 Garant, Systemp.c&b, and Trim) and one light-...

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Main Authors: Simon Daniel Schulz, Tobias Laquai, Klaus Kümmerer, Richard Bolek, Volker Mersch-Sundermann, Olga Polydorou
Format: Article
Language:English
Published: Hindawi Limited 2015-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2015/617407
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spelling doaj-b73c7d9c8bdb470884d70a0ebbd5a0002020-11-25T00:44:48ZengHindawi LimitedInternational Journal of Polymer Science1687-94221687-94302015-01-01201510.1155/2015/617407617407Elution of Monomers from Provisional Composite MaterialsSimon Daniel Schulz0Tobias Laquai1Klaus Kümmerer2Richard Bolek3Volker Mersch-Sundermann4Olga Polydorou5Department of Oral Biotechnology, University Medical Center Freiburg, Center of Dental Medicine, Hugstetter Straße 55, 79106 Freiburg, GermanyDepartment of Operative Dentistry and Periodontology, University Medical Center Freiburg, Center of Dental Medicine, Hugstetter Straße 55, 79106 Freiburg, GermanyDepartment of Environmental Health Sciences, University Medical Center Freiburg, Breisacher Straße 115 b, 79106 Freiburg, GermanyDepartment of Environmental Health Sciences, University Medical Center Freiburg, Breisacher Straße 115 b, 79106 Freiburg, GermanyDepartment of Environmental Health Sciences, University Medical Center Freiburg, Breisacher Straße 115 b, 79106 Freiburg, GermanyDepartment of Operative Dentistry and Periodontology, University Medical Center Freiburg, Center of Dental Medicine, Hugstetter Straße 55, 79106 Freiburg, GermanyThe aim of this study was to evaluate the elution of substances from different materials used for the manufacturing of temporary indirect restorations, after storage in saliva and ethanol 75%. 10 samples of three chemically cured materials (Protemp 3 Garant, Systemp.c&b, and Trim) and one light-cured material (Clip F) were stored in saliva and ethanol 75% for 24 h, 7, and days 28 days. From the storage media at each time period, samples were prepared and analysed by LC-MS/MS, in order to access the elution of monomers. The results differed among the materials (P ≤ 0.05). No monomers were detected in the samples of Protemp 3 Garant and Clip F. Substances were detected only in ethanol samples of Systemp.c&b and Trim. The amount of BisGMA, TEGDMA, and UDMA 2 released from Systemp.c&b was higher compared to Trim. Storage time affected the release of substances (P ≤ 0.05). The highest release was observed within the first 24 h. It can be concluded that provisional resin composite materials do not show high release of monomers and this release is material dependent. However, the detection of additional peaks during the analysis, suggesting the formation of by-products of the eluted substances, may not be in favour of these materials with respect to their toxicity.http://dx.doi.org/10.1155/2015/617407
collection DOAJ
language English
format Article
sources DOAJ
author Simon Daniel Schulz
Tobias Laquai
Klaus Kümmerer
Richard Bolek
Volker Mersch-Sundermann
Olga Polydorou
spellingShingle Simon Daniel Schulz
Tobias Laquai
Klaus Kümmerer
Richard Bolek
Volker Mersch-Sundermann
Olga Polydorou
Elution of Monomers from Provisional Composite Materials
International Journal of Polymer Science
author_facet Simon Daniel Schulz
Tobias Laquai
Klaus Kümmerer
Richard Bolek
Volker Mersch-Sundermann
Olga Polydorou
author_sort Simon Daniel Schulz
title Elution of Monomers from Provisional Composite Materials
title_short Elution of Monomers from Provisional Composite Materials
title_full Elution of Monomers from Provisional Composite Materials
title_fullStr Elution of Monomers from Provisional Composite Materials
title_full_unstemmed Elution of Monomers from Provisional Composite Materials
title_sort elution of monomers from provisional composite materials
publisher Hindawi Limited
series International Journal of Polymer Science
issn 1687-9422
1687-9430
publishDate 2015-01-01
description The aim of this study was to evaluate the elution of substances from different materials used for the manufacturing of temporary indirect restorations, after storage in saliva and ethanol 75%. 10 samples of three chemically cured materials (Protemp 3 Garant, Systemp.c&b, and Trim) and one light-cured material (Clip F) were stored in saliva and ethanol 75% for 24 h, 7, and days 28 days. From the storage media at each time period, samples were prepared and analysed by LC-MS/MS, in order to access the elution of monomers. The results differed among the materials (P ≤ 0.05). No monomers were detected in the samples of Protemp 3 Garant and Clip F. Substances were detected only in ethanol samples of Systemp.c&b and Trim. The amount of BisGMA, TEGDMA, and UDMA 2 released from Systemp.c&b was higher compared to Trim. Storage time affected the release of substances (P ≤ 0.05). The highest release was observed within the first 24 h. It can be concluded that provisional resin composite materials do not show high release of monomers and this release is material dependent. However, the detection of additional peaks during the analysis, suggesting the formation of by-products of the eluted substances, may not be in favour of these materials with respect to their toxicity.
url http://dx.doi.org/10.1155/2015/617407
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