(N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)

(N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)

The title compound, [RhCl(C8H12)(C14H12N2OS)], is a rhodium(I) derivative with a functionalized thiourea ligand. Despite the presence of several heteroatoms, the thiourea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square...

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Main Authors: P. D. Riekert Kotze, Andreas Roodt, Johan A. Venter, Stefanus Otto
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810029740
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spelling doaj-b6c229c1033245439be6bdcd0798df842020-11-25T00:20:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m1028m102910.1107/S1600536810029740(N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)P. D. Riekert KotzeAndreas RoodtJohan A. VenterStefanus OttoThe title compound, [RhCl(C8H12)(C14H12N2OS)], is a rhodium(I) derivative with a functionalized thiourea ligand. Despite the presence of several heteroatoms, the thiourea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square planar about the RhI atom, with two bonds to the π-electrons of the 1,5-cyclooctadiene ligand, one bond to the Cl− ligand and one bond to the S atom of the thiourea ligand. The molecular structure is stabilized by intramolecular N—H...O and N—H...Cl hydrogen bonding. Intermolecular N—H...O hydrogen-bonding interactions lead to the formation of layers extending parallel to (011). http://scripts.iucr.org/cgi-bin/paper?S1600536810029740
collection DOAJ
language English
format Article
sources DOAJ
author P. D. Riekert Kotze
Andreas Roodt
Johan A. Venter
Stefanus Otto
spellingShingle P. D. Riekert Kotze
Andreas Roodt
Johan A. Venter
Stefanus Otto
(N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
Acta Crystallographica Section E
author_facet P. D. Riekert Kotze
Andreas Roodt
Johan A. Venter
Stefanus Otto
author_sort P. D. Riekert Kotze
title (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
title_short (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
title_full (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
title_fullStr (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
title_full_unstemmed (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
title_sort (n-benzoyl-n′-phenylthiourea-κs)chlorido(η4-1,5-cyclooctadiene)rhodium(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description The title compound, [RhCl(C8H12)(C14H12N2OS)], is a rhodium(I) derivative with a functionalized thiourea ligand. Despite the presence of several heteroatoms, the thiourea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square planar about the RhI atom, with two bonds to the π-electrons of the 1,5-cyclooctadiene ligand, one bond to the Cl− ligand and one bond to the S atom of the thiourea ligand. The molecular structure is stabilized by intramolecular N—H...O and N—H...Cl hydrogen bonding. Intermolecular N—H...O hydrogen-bonding interactions lead to the formation of layers extending parallel to (011).
url http://scripts.iucr.org/cgi-bin/paper?S1600536810029740
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AT johanaventer nbenzoylnamp8242phenylthioureaamp954schloridoamp951415cyclooctadienerhodiumi
AT stefanusotto nbenzoylnamp8242phenylthioureaamp954schloridoamp951415cyclooctadienerhodiumi
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