| Summary: | The bis(pyrazole)zinc(II) benzoate complexes bis(3,5-diphenylpyrazole)zinc(II) benzoate (1), bis(3,5-diphenylpyrazole)zinc(II) 3,5-dinitrobenzoate (2), bis(3,5-diphenylpyrazole)zinc(II) 4-hydroxybenzoate (3), and bis(3,5-di-tert-butylpyrazole)zinc(II) 2-chlorobenzoate (4) were synthesized from the reaction of 3,5-diphenylpyrazole (L1) or 3,5-di-tert-butylpyrazole (L2), zinc(II) acetate and the appropriate benzene carboxylic acid. The molecular structure of complex 2 confirmed that these zinc(II) benzoate complexes adopt a 4-coordinate tetrahedral geometry. All four complexes were screened as catalysts for the copolymerization of carbon dioxide (CO2) and cyclohexene oxide (CHO) and were found to be active for the formation of poly(cyclohexene carbonate) (PCHC) at CO2 pressures as low as 1.0 MPa under solvent-free conditions and without the use of a co-catalyst. At some reaction condition, most of the catalysts produced PCHC with high carbonate content of up to 98% and a good amount of cyclic cyclohexene carbonate (CCHC). The copolymers produced have low to moderate molecular weights (5200–12300 g/mol) and with polydispersity indices that vary from 1.19 to 2.50. Matrix Assisted Laser Desorption/Ionization-Time of Flight Mass Spectra (MALDI-TOF MS) of these copolymers showed they have benzoate and hydroxyl end groups.
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