A Well-Defined {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes

A Well-Defined {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} Complex Catalyzed Hiyama Coupling of Aryl Bromides with Arylsilanes

A palladium (II) complex {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating.

Bibliographic Details
Main Authors: Mengping Guo, Leiqing Fu, Jiamin Li, Lanjiang Zhou, Yanping Kang
Format: Article
Language:English
Published: MDPI AG 2016-07-01
Series:Molecules
Subjects:
palladium (II) complex
Hiyama cross-coupling reaction
unsymmetrical biaryls
synthetic method
Online Access:http://www.mdpi.com/1420-3049/21/8/987
Description
Summary:A palladium (II) complex {[(PhCH2O)2P(CH3)2CHNCH(CH3)2]2PdCl2} catalyzed Hiyama cross-coupling reaction between aryl bromides and arylsilanes has been developed. The substituted biaryls were produced in moderate to high yields, regardless of electron-withdrawing or electron-donating.
ISSN:1420-3049

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