Adeninium cytosinium sulfate

Adeninium cytosinium sulfate

In the title compound, C5H6N5+·C4H6N3O+·SO42−, the adeninium (AdH+) and cytosinium (CytH+) cations and sulfate dianion are involved in a three-dimensional hydrogen-bonding network with four different modes, viz. AdH+...AdH+, AdH+...CytH+, AdH+...SO42&#...

Full description

Bibliographic Details
Main Authors: Aouatef Cherouana, Raja Bousboua, Lamia Bendjeddou, Slimane Dahaoui, Claude Lecomte
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809034023
id doaj-b635d937690e49248d40962f763c90b1
record_format Article
spelling doaj-b635d937690e49248d40962f763c90b12020-11-25T01:13:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659o2285o228610.1107/S1600536809034023Adeninium cytosinium sulfateAouatef CherouanaRaja BousbouaLamia BendjeddouSlimane DahaouiClaude LecomteIn the title compound, C5H6N5+·C4H6N3O+·SO42−, the adeninium (AdH+) and cytosinium (CytH+) cations and sulfate dianion are involved in a three-dimensional hydrogen-bonding network with four different modes, viz. AdH+...AdH+, AdH+...CytH+, AdH+...SO42− and CytH+...SO42−. The adeninium cations form N—H...N dimers through the Hoogsteen faces, generating a characteristic R22(10) motif. This AdH+...AdH+ hydrogen bond in combination with AdH+...CytH+ H-bonds leads to two-dimensional cationic ribbons parallel to the a axis. The sulfate anions interlink the ribbons into a three-dimensional hydrogen-bonding network and thus reinforce the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536809034023
collection DOAJ
language English
format Article
sources DOAJ
author Aouatef Cherouana
Raja Bousboua
Lamia Bendjeddou
Slimane Dahaoui
Claude Lecomte
spellingShingle Aouatef Cherouana
Raja Bousboua
Lamia Bendjeddou
Slimane Dahaoui
Claude Lecomte
Adeninium cytosinium sulfate
Acta Crystallographica Section E
author_facet Aouatef Cherouana
Raja Bousboua
Lamia Bendjeddou
Slimane Dahaoui
Claude Lecomte
author_sort Aouatef Cherouana
title Adeninium cytosinium sulfate
title_short Adeninium cytosinium sulfate
title_full Adeninium cytosinium sulfate
title_fullStr Adeninium cytosinium sulfate
title_full_unstemmed Adeninium cytosinium sulfate
title_sort adeninium cytosinium sulfate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description In the title compound, C5H6N5+·C4H6N3O+·SO42−, the adeninium (AdH+) and cytosinium (CytH+) cations and sulfate dianion are involved in a three-dimensional hydrogen-bonding network with four different modes, viz. AdH+...AdH+, AdH+...CytH+, AdH+...SO42− and CytH+...SO42−. The adeninium cations form N—H...N dimers through the Hoogsteen faces, generating a characteristic R22(10) motif. This AdH+...AdH+ hydrogen bond in combination with AdH+...CytH+ H-bonds leads to two-dimensional cationic ribbons parallel to the a axis. The sulfate anions interlink the ribbons into a three-dimensional hydrogen-bonding network and thus reinforce the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809034023
work_keys_str_mv AT aouatefcherouana adeniniumcytosiniumsulfate
AT rajabousboua adeniniumcytosiniumsulfate
AT lamiabendjeddou adeniniumcytosiniumsulfate
AT slimanedahaoui adeniniumcytosiniumsulfate
AT claudelecomte adeniniumcytosiniumsulfate
_version_ 1725159459295068160

Similar Items