Cyanidophenyltris(trimethylphosphine)cobalt(II)

Cyanidophenyltris(trimethylphosphine)cobalt(II)

The title molecule, [Co(C6H5)(CN)(C3H9P)3], lies on a crystallographic mirror plane with the CoII ion coordinated in a distorted square-pyramidal environment with one of the P atoms in the apical position. In the basal plane, the phenyl substituent is trans to the cyanide group with a C—Co...

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Bibliographic Details
Main Authors: Fengli Yu, Qibao Wang, Xiaoyan Li
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807064781
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spelling doaj-b622152f9ec54502b22c8d3740b764072020-11-25T01:57:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m112m11210.1107/S1600536807064781Cyanidophenyltris(trimethylphosphine)cobalt(II)Fengli YuQibao WangXiaoyan LiThe title molecule, [Co(C6H5)(CN)(C3H9P)3], lies on a crystallographic mirror plane with the CoII ion coordinated in a distorted square-pyramidal environment with one of the P atoms in the apical position. In the basal plane, the phenyl substituent is trans to the cyanide group with a C—Co—C angle which is significantly distorted from linearity.http://scripts.iucr.org/cgi-bin/paper?S1600536807064781
collection DOAJ
language English
format Article
sources DOAJ
author Fengli Yu
Qibao Wang
Xiaoyan Li
spellingShingle Fengli Yu
Qibao Wang
Xiaoyan Li
Cyanidophenyltris(trimethylphosphine)cobalt(II)
Acta Crystallographica Section E
author_facet Fengli Yu
Qibao Wang
Xiaoyan Li
author_sort Fengli Yu
title Cyanidophenyltris(trimethylphosphine)cobalt(II)
title_short Cyanidophenyltris(trimethylphosphine)cobalt(II)
title_full Cyanidophenyltris(trimethylphosphine)cobalt(II)
title_fullStr Cyanidophenyltris(trimethylphosphine)cobalt(II)
title_full_unstemmed Cyanidophenyltris(trimethylphosphine)cobalt(II)
title_sort cyanidophenyltris(trimethylphosphine)cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The title molecule, [Co(C6H5)(CN)(C3H9P)3], lies on a crystallographic mirror plane with the CoII ion coordinated in a distorted square-pyramidal environment with one of the P atoms in the apical position. In the basal plane, the phenyl substituent is trans to the cyanide group with a C—Co—C angle which is significantly distorted from linearity.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807064781
work_keys_str_mv AT fengliyu cyanidophenyltristrimethylphosphinecobaltii
AT qibaowang cyanidophenyltristrimethylphosphinecobaltii
AT xiaoyanli cyanidophenyltristrimethylphosphinecobaltii
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