Synthesis and structure of the dimericdiorganotinhydroxyphosphinate [t-Bu2Sn(OH)OPPh2O)]2

The reaction of (C6F5)3BOPPh2OH (prepared in situ from the rather weak Brønsted acid Ph2PO2H and the strong Lewis acid B(C6F5)3) with (t-Bu2SnO)3 provided the dinuclear complex [t-Bu2Sn(OH)OPPh2O)]2, which was investigated by X-ray crystallography.

Bibliographic Details
Main Authors: Kather Ralf, Lork Enno, Beckmann Jens
Format: Article
Language:English
Published: De Gruyter 2017-04-01
Series:Main Group Metal Chemistry
Subjects:
tin
Online Access:https://doi.org/10.1515/mgmc-2017-0017