Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate
In the title hydrated molecular salt, C8H12N+·C6H4NO3−·H2O, the conformation of the side chain in the cation is anti [C—C—C—N = 179.62 (12)°] and the dihedral angle between the aromatic ring and the nitro group in the anion is 3.34 (11)°. In the crystal, the components are linked by O—H...O and N—H....
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014-12-01
|
| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814025318 |
| id |
doaj-b5a958f218804f0683b2a6535374168d |
|---|---|
| record_format |
Article |
| spelling |
doaj-b5a958f218804f0683b2a6535374168d2020-11-25T01:13:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-12-017012o1280o128010.1107/S1600536814025318hb7318Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrateN. Swarna Sowmya0S. Sampathkrishnan1S. Sudhahar2R. Mohan Kumar3G. Chakkaravarthi4Department of Applied Physics, Sri Venkateswara College of Engineering, Chennai 602 117, IndiaDepartment of Applied Physics, Sri Venkateswara College of Engineering, Chennai 602 117, IndiaDepartment of Physics, Presidency College, Chennai 600 005, IndiaDepartment of Physics, Presidency College, Chennai 600 005, IndiaDepartment of Physics, CPCL Polytechnic College, Chennai 600 068, IndiaIn the title hydrated molecular salt, C8H12N+·C6H4NO3−·H2O, the conformation of the side chain in the cation is anti [C—C—C—N = 179.62 (12)°] and the dihedral angle between the aromatic ring and the nitro group in the anion is 3.34 (11)°. In the crystal, the components are linked by O—H...O and N—H...O hydrogen bonds, generating (10-1) sheets, which feature R44(21) loops. The sheets interact by weak aromatic π–π stacking interactions [centroid–centroid distance = 3.896 (3) Å], forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536814025318crystal structure2-phenylethylaminium4-nitrophenolatehydrated saltO—H...O and N—H...O hydrogen bondsπ–π stacking interactions |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
N. Swarna Sowmya S. Sampathkrishnan S. Sudhahar R. Mohan Kumar G. Chakkaravarthi |
| spellingShingle |
N. Swarna Sowmya S. Sampathkrishnan S. Sudhahar R. Mohan Kumar G. Chakkaravarthi Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate Acta Crystallographica Section E crystal structure 2-phenylethylaminium 4-nitrophenolate hydrated salt O—H...O and N—H...O hydrogen bonds π–π stacking interactions |
| author_facet |
N. Swarna Sowmya S. Sampathkrishnan S. Sudhahar R. Mohan Kumar G. Chakkaravarthi |
| author_sort |
N. Swarna Sowmya |
| title |
Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate |
| title_short |
Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate |
| title_full |
Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate |
| title_fullStr |
Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate |
| title_full_unstemmed |
Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate |
| title_sort |
crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2014-12-01 |
| description |
In the title hydrated molecular salt, C8H12N+·C6H4NO3−·H2O, the conformation of the side chain in the cation is anti [C—C—C—N = 179.62 (12)°] and the dihedral angle between the aromatic ring and the nitro group in the anion is 3.34 (11)°. In the crystal, the components are linked by O—H...O and N—H...O hydrogen bonds, generating (10-1) sheets, which feature R44(21) loops. The sheets interact by weak aromatic π–π stacking interactions [centroid–centroid distance = 3.896 (3) Å], forming a three-dimensional network. |
| topic |
crystal structure 2-phenylethylaminium 4-nitrophenolate hydrated salt O—H...O and N—H...O hydrogen bonds π–π stacking interactions |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814025318 |
| work_keys_str_mv |
AT nswarnasowmya crystalstructureof2phenylethylaminium4nitrophenolatemonohydrate AT ssampathkrishnan crystalstructureof2phenylethylaminium4nitrophenolatemonohydrate AT ssudhahar crystalstructureof2phenylethylaminium4nitrophenolatemonohydrate AT rmohankumar crystalstructureof2phenylethylaminium4nitrophenolatemonohydrate AT gchakkaravarthi crystalstructureof2phenylethylaminium4nitrophenolatemonohydrate |
| _version_ |
1725162714848821248 |