| Summary: | Solar energy can be converted into useful energy via photovoltaic cells or with a photothermal absorber. While these technologies are well-developed and commercially viable, significant benefits can be realised by pulling these two technologies together in photovoltaic/thermal (PV/T) systems which can provide both heat and electricity from a single collector. Emerging configurations in the PV/T field aim to incorporate micro and/or nanotechnology to boost total solar utilisation even further. One example of this is the nanofluid-based PV/T collector. This type of solar collector utilises nanofluids—suspensions of nanoparticles in traditional heat transfer fluids—as both an optical filter and as a thermal absorber. This concept seeks to harvest the whole solar spectrum at its highest thermodynamic potential through specially engineered nanofluids which transmit the portion of solar spectrum corresponding to the PV response curve while absorbing the rest as heat. Depending on the nanoparticle concentration, employing nanofluids in a flowing system may come with a price—an efficiency penalty in the form of increased pumping power (due to increased viscosity). Similarly, microchannel-based heat exchangers have been shown to increase heat transfer, but they may also pay the price of high pumping power due to additional wall-shear-related pressure drop (i.e., more no-slip boundary area). To develop a novel PV/T configuration which pulls together the advantages of these micro and nanotechnologies <i>with minimal pumping power requirements</i>, the present study experimentally investigated the use of nanofluids in patterned hydrophobic microchannels. It was found that slip with the walls reduced the impact of the increased viscosity of nanofluids by reducing the pressure drop on average 17% relative to a smooth channel. In addition, flowing a selective Ag/SiO<sub>2</sub> core–shell nanofluid over a silicon surface (simulating a PV cell underneath the fluid) provided a 20% increase in solar thermal conversion efficiency and ~3% higher stagnation temperature than using pure water. This demonstrates the potential of this proposed system for extracting more useful energy from the same incident flux. Although no electrical energy was extracted from the underlying patterned silicon, this study highlights potential a new development path for micro and nanotechnology to be integrated into next-generation PV/T solar collectors.
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