Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate

Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate

The asymmetric unit of the title compound, [Pd2(C9H12NTe)2Cl2]·0.5CH2Cl2, contains two half-molecules, each lying on a twofold rotation axis; each molecule is chiral and of the same enantiomer. This is only possible as the molecule has a hinged cis arrangement about the Pd2+ coordinatio...

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Main Authors: Ray J. Butcher, Tapash Chakravorty, Harkesh B. Singh
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812000104
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spelling doaj-b4aecc77145945999ad3e37696d6740b2020-11-25T02:46:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m141m14210.1107/S1600536812000104Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvateRay J. ButcherTapash ChakravortyHarkesh B. SinghThe asymmetric unit of the title compound, [Pd2(C9H12NTe)2Cl2]·0.5CH2Cl2, contains two half-molecules, each lying on a twofold rotation axis; each molecule is chiral and of the same enantiomer. This is only possible as the molecule has a hinged cis arrangement about the Pd2+ coordination spheres. For this hinged dimeric structure, the angles between the two coordination planes in each molecule are 21.59 (4) and 22.10 (4)°. This hinged cis arrangement also allows the two molecules to form pairs linked by secondary interactions between the Pd and Te atoms of an adjoining molecule, leading to a tetrameric overall structure. C—H...Cl interactions consolidate the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536812000104
collection DOAJ
language English
format Article
sources DOAJ
author Ray J. Butcher
Tapash Chakravorty
Harkesh B. Singh
spellingShingle Ray J. Butcher
Tapash Chakravorty
Harkesh B. Singh
Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate
Acta Crystallographica Section E
author_facet Ray J. Butcher
Tapash Chakravorty
Harkesh B. Singh
author_sort Ray J. Butcher
title Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate
title_short Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate
title_full Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate
title_fullStr Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate
title_full_unstemmed Bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(II)] dichloromethane hemisolvate
title_sort bis{μ-2-[(dimethylamino)methyl]benzenetellurolato}bis[chloridopalladium(ii)] dichloromethane hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description The asymmetric unit of the title compound, [Pd2(C9H12NTe)2Cl2]·0.5CH2Cl2, contains two half-molecules, each lying on a twofold rotation axis; each molecule is chiral and of the same enantiomer. This is only possible as the molecule has a hinged cis arrangement about the Pd2+ coordination spheres. For this hinged dimeric structure, the angles between the two coordination planes in each molecule are 21.59 (4) and 22.10 (4)°. This hinged cis arrangement also allows the two molecules to form pairs linked by secondary interactions between the Pd and Te atoms of an adjoining molecule, leading to a tetrameric overall structure. C—H...Cl interactions consolidate the crystal packing.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812000104
work_keys_str_mv AT rayjbutcher bisamp9562dimethylaminomethylbenzenetellurolatobischloridopalladiumiidichloromethanehemisolvate
AT tapashchakravorty bisamp9562dimethylaminomethylbenzenetellurolatobischloridopalladiumiidichloromethanehemisolvate
AT harkeshbsingh bisamp9562dimethylaminomethylbenzenetellurolatobischloridopalladiumiidichloromethanehemisolvate
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