Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate

Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate

The title compound {systematic name: bis[1,4(η5)-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ6P:O;3:4κ6O:P-μ-oxalato-2:3κ4O1,O2:O1′,O2′-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co2V2(C5H5...

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Bibliographic Details
Main Authors: Alexander E. Anderson, Craig C. McLauchlan
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808024458
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spelling doaj-b4983bb8a7bd4ee1a9670f5caee947ee2020-11-25T00:46:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1129m113010.1107/S1600536808024458Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalateAlexander E. AndersonCraig C. McLauchlanThe title compound {systematic name: bis[1,4(η5)-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ6P:O;3:4κ6O:P-μ-oxalato-2:3κ4O1,O2:O1′,O2′-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co2V2(C5H5)2(C2O4)(C4H10O3P)6O2], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclopentadienyl ring. The unique V atom has six O atom neighbors in an approximately octahedral arrangement; the V—O bond trans to the V=O bond is significantly lengthened.http://scripts.iucr.org/cgi-bin/paper?S1600536808024458
collection DOAJ
language English
format Article
sources DOAJ
author Alexander E. Anderson
Craig C. McLauchlan
spellingShingle Alexander E. Anderson
Craig C. McLauchlan
Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate
Acta Crystallographica Section E
author_facet Alexander E. Anderson
Craig C. McLauchlan
author_sort Alexander E. Anderson
title Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_short Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_full Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_fullStr Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_full_unstemmed Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate
title_sort bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3p,p′,p′′)cobaltate(iii)-κ3o,o′,o′′]oxovanadium(iv)}-μ-oxalate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-09-01
description The title compound {systematic name: bis[1,4(η5)-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ6P:O;3:4κ6O:P-μ-oxalato-2:3κ4O1,O2:O1′,O2′-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co2V2(C5H5)2(C2O4)(C4H10O3P)6O2], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclopentadienyl ring. The unique V atom has six O atom neighbors in an approximately octahedral arrangement; the V—O bond trans to the V=O bond is significantly lengthened.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808024458
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AT craigcmclauchlan bis9515cyclopentadienyltrisdiethylphosphito9543pp8242p82428242cobaltateiii9543oo8242o82428242oxovanadiumiv956oxalate
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