Bis{[(η5)-cyclopentadienyl]tris(diethyl phosphito-κ3P,P′,P′′)cobaltate(III)-κ3O,O′,O′′]oxovanadium(IV)}-μ-oxalate
The title compound {systematic name: bis[1,4(η5)-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ6P:O;3:4κ6O:P-μ-oxalato-2:3κ4O1,O2:O1′,O2′-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co2V2(C5H5...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808024458 |
| Summary: | The title compound {systematic name: bis[1,4(η5)-cyclopentadienyl]hexakis(μ-diethyl phosphito)-1:2κ6P:O;3:4κ6O:P-μ-oxalato-2:3κ4O1,O2:O1′,O2′-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co2V2(C5H5)2(C2O4)(C4H10O3P)6O2], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclopentadienyl ring. The unique V atom has six O atom neighbors in an approximately octahedral arrangement; the V—O bond trans to the V=O bond is significantly lengthened. |
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| ISSN: | 1600-5368 |