A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)

A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)

In the structure of the title compound, [PdCl2(C5H5N)2], the PdII atom is located on an inversion centre and the pyridine rings are coplanar. There is intermolecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1)&...

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Main Authors: Hon Man Lee, Chuang-Yi Liao
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808033552
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spelling doaj-b481766039bb4cbdab397f3ec80e0d5b2020-11-25T01:35:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1447m144710.1107/S1600536808033552A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)Hon Man LeeChuang-Yi LiaoIn the structure of the title compound, [PdCl2(C5H5N)2], the PdII atom is located on an inversion centre and the pyridine rings are coplanar. There is intermolecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993). Acta Cryst. C49, 84–85; Liao & Lee (2006). Acta Cryst. E62, m680–m681].http://scripts.iucr.org/cgi-bin/paper?S1600536808033552
collection DOAJ
language English
format Article
sources DOAJ
author Hon Man Lee
Chuang-Yi Liao
spellingShingle Hon Man Lee
Chuang-Yi Liao
A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)
Acta Crystallographica Section E
author_facet Hon Man Lee
Chuang-Yi Liao
author_sort Hon Man Lee
title A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)
title_short A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)
title_full A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)
title_fullStr A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)
title_full_unstemmed A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)
title_sort new monoclinic polymorph of trans-dichloridodipyridinepalladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-11-01
description In the structure of the title compound, [PdCl2(C5H5N)2], the PdII atom is located on an inversion centre and the pyridine rings are coplanar. There is intermolecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993). Acta Cryst. C49, 84–85; Liao & Lee (2006). Acta Cryst. E62, m680–m681].
url http://scripts.iucr.org/cgi-bin/paper?S1600536808033552
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