1-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea
In the N-substituted benzoylthiourea, C24H23N5OS, the benzoylthiourea unit is non-planar (r.m.s. deviation = 0.126 Å). The aliphatic part of the tetrahydroquinoline fused-ring system is disordered over two positions in a 0.592 (5):0.408 (5) rati...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811033046 |
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doaj-b46c91ffac0c4d7dac2193c60c4f18c82020-11-25T02:16:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679o2430o243010.1107/S16005368110330461-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thioureaAbdullah M. AsiriHassan M. FaidallahAbdulrahman O. Al-YoubiKhalid A. AlamrySeik Weng NgIn the N-substituted benzoylthiourea, C24H23N5OS, the benzoylthiourea unit is non-planar (r.m.s. deviation = 0.126 Å). The aliphatic part of the tetrahydroquinoline fused-ring system is disordered over two positions in a 0.592 (5):0.408 (5) ratio. The pyridine and pyrrole rings are twisted by 55.2 (1)° in order to avoid crowding of their respective substituents. Pairs of molecules are linked by N—H...N hydrogen bonds, forming centrosymmetric dimers. Furthermore, an intramolecular N—H...O hydrogen bond stabilizes the molecular conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536811033046 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Abdullah M. Asiri Hassan M. Faidallah Abdulrahman O. Al-Youbi Khalid A. Alamry Seik Weng Ng |
| spellingShingle |
Abdullah M. Asiri Hassan M. Faidallah Abdulrahman O. Al-Youbi Khalid A. Alamry Seik Weng Ng 1-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea Acta Crystallographica Section E |
| author_facet |
Abdullah M. Asiri Hassan M. Faidallah Abdulrahman O. Al-Youbi Khalid A. Alamry Seik Weng Ng |
| author_sort |
Abdullah M. Asiri |
| title |
1-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea |
| title_short |
1-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea |
| title_full |
1-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea |
| title_fullStr |
1-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea |
| title_full_unstemmed |
1-Benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1H-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea |
| title_sort |
1-benzoyl-3-[3-cyano-8-methyl-4-(1-methyl-1h-pyrrol-2-yl)-5,6,7,8-tetrahydroquinolin-2-yl]thiourea |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-09-01 |
| description |
In the N-substituted benzoylthiourea, C24H23N5OS, the benzoylthiourea unit is non-planar (r.m.s. deviation = 0.126 Å). The aliphatic part of the tetrahydroquinoline fused-ring system is disordered over two positions in a 0.592 (5):0.408 (5) ratio. The pyridine and pyrrole rings are twisted by 55.2 (1)° in order to avoid crowding of their respective substituents. Pairs of molecules are linked by N—H...N hydrogen bonds, forming centrosymmetric dimers. Furthermore, an intramolecular N—H...O hydrogen bond stabilizes the molecular conformation. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811033046 |
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