Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-Templating

Porous α-SiAlON ceramics were fabricated using the camphene-based unidirectional freeze casting method, in which a gradient porous structure was formed as a result of the decreased solidification velocity in the freezing direction. Microstructure, porosity and pore size distribution of diff...

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Main Authors: Zhaoping Hou, Feng Ye, Qiang Liu, Limeng Liu, Haiwei Jiang, Shaowei Zhang
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/12/5/687
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spelling doaj-b459fd7ebe8c48ef90902ee62445b0be2020-11-24T23:31:15ZengMDPI AGMaterials1996-19442019-02-0112568710.3390/ma12050687ma12050687Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-TemplatingZhaoping Hou0Feng Ye1Qiang Liu2Limeng Liu3Haiwei Jiang4Shaowei Zhang5College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaSchool of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, ChinaSchool of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, ChinaSchool of Materials Science and Engineering, North Minzu University, Yinchuan 750021, ChinaCollege of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaCollege of Engineering, Mathematics and Physical Sciences, University of Exeter, Exeter EX4 4QF, UKPorous α-SiAlON ceramics were fabricated using the camphene-based unidirectional freeze casting method, in which a gradient porous structure was formed as a result of the decreased solidification velocity in the freezing direction. Microstructure, porosity and pore size distribution of different parts of as-prepared samples were examined and compared, and correlated with their mechanical properties. For a given solid loading, the overall pore size and porosity of the top part were greater than those of the bottom part. Interestingly, despite its higher porosity, the flexural strength and fracture toughness of the top part were both higher than those of the bottom part, suggesting that apart from porosity, pore morphology and size affected mechanical properties of as-prepared porous α-SiAlON ceramics.https://www.mdpi.com/1996-1944/12/5/687camphene-templated porous α-SiAlONporositypore sizemechanical properties
collection DOAJ
language English
format Article
sources DOAJ
author Zhaoping Hou
Feng Ye
Qiang Liu
Limeng Liu
Haiwei Jiang
Shaowei Zhang
spellingShingle Zhaoping Hou
Feng Ye
Qiang Liu
Limeng Liu
Haiwei Jiang
Shaowei Zhang
Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-Templating
Materials
camphene-templated porous α-SiAlON
porosity
pore size
mechanical properties
author_facet Zhaoping Hou
Feng Ye
Qiang Liu
Limeng Liu
Haiwei Jiang
Shaowei Zhang
author_sort Zhaoping Hou
title Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-Templating
title_short Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-Templating
title_full Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-Templating
title_fullStr Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-Templating
title_full_unstemmed Pore Architectures and Mechanical Properties of Porous α-SiAlON Ceramics Fabricated via Unidirectional Freeze Casting Based on Camphene-Templating
title_sort pore architectures and mechanical properties of porous α-sialon ceramics fabricated via unidirectional freeze casting based on camphene-templating
publisher MDPI AG
series Materials
issn 1996-1944
publishDate 2019-02-01
description Porous α-SiAlON ceramics were fabricated using the camphene-based unidirectional freeze casting method, in which a gradient porous structure was formed as a result of the decreased solidification velocity in the freezing direction. Microstructure, porosity and pore size distribution of different parts of as-prepared samples were examined and compared, and correlated with their mechanical properties. For a given solid loading, the overall pore size and porosity of the top part were greater than those of the bottom part. Interestingly, despite its higher porosity, the flexural strength and fracture toughness of the top part were both higher than those of the bottom part, suggesting that apart from porosity, pore morphology and size affected mechanical properties of as-prepared porous α-SiAlON ceramics.
topic camphene-templated porous α-SiAlON
porosity
pore size
mechanical properties
url https://www.mdpi.com/1996-1944/12/5/687
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