Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate

Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate

The title solvated salt, [NiCl(C10H8N2)2(H2O)]Cl·CHCl3·0.5H2O, contains a mononuclear NiII complex cation with 2,2′-bipyridine, chloride and aqua ligands forming a slightly distorted ClN4O octahedral coordination set. The charge of the cation is balanced by a chloride anion. In the crystal, half a w...

Full description

Bibliographic Details
Main Authors: Eugenia Vasileiadou, Panagiotis A. Angaridis, Raphael G. Raptis, Logesh Mathivathanan
Format: Article
Language:English
Published: International Union of Crystallography 2016-11-01
Series:IUCrData
Subjects:
crystal structure
nickel(II)
2,2′-bipyridine
octahedral coordination environment
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616018344
id doaj-b43a582dd8444688ac162b5db76bae70
record_format Article
spelling doaj-b43a582dd8444688ac162b5db76bae702020-11-24T21:02:53ZengInternational Union of CrystallographyIUCrData2414-31462016-11-01111x16183410.1107/S2414314616018344wm5333Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrateEugenia Vasileiadou0Panagiotis A. Angaridis1Raphael G. Raptis2Logesh Mathivathanan3Department of Chemistry and Biochemistry, Florida International University, 11200 SW 8th Street, Miami, FL 33199, USADepartment of Chemistry, Aristotle University of Thessaloniki, University Campus, Thessaloniki, 54124, GreeceDepartment of Chemistry and Biochemistry, Florida International University, 11200 SW 8th Street, Miami, FL 33199, USADepartment of Chemistry and Biochemistry, Florida International University, 11200 SW 8th Street, Miami, FL 33199, USAThe title solvated salt, [NiCl(C10H8N2)2(H2O)]Cl·CHCl3·0.5H2O, contains a mononuclear NiII complex cation with 2,2′-bipyridine, chloride and aqua ligands forming a slightly distorted ClN4O octahedral coordination set. The charge of the cation is balanced by a chloride anion. In the crystal, half a water molecule and a chloroform solvent molecule are present per formula unit. Individual components are held together by O—H...Cl hydrogen bonding and π–π interactions.http://scripts.iucr.org/cgi-bin/paper?S2414314616018344crystal structurenickel(II)2,2′-bipyridineoctahedral coordination environment
collection DOAJ
language English
format Article
sources DOAJ
author Eugenia Vasileiadou
Panagiotis A. Angaridis
Raphael G. Raptis
Logesh Mathivathanan
spellingShingle Eugenia Vasileiadou
Panagiotis A. Angaridis
Raphael G. Raptis
Logesh Mathivathanan
Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate
IUCrData
crystal structure
nickel(II)
2,2′-bipyridine
octahedral coordination environment
author_facet Eugenia Vasileiadou
Panagiotis A. Angaridis
Raphael G. Raptis
Logesh Mathivathanan
author_sort Eugenia Vasileiadou
title Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate
title_short Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate
title_full Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate
title_fullStr Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate
title_full_unstemmed Aquabis(2,2′-bipyridine-κ2N,N′)chloridonickel(II) chloride chloroform monosolvate hemihydrate
title_sort aquabis(2,2′-bipyridine-κ2n,n′)chloridonickel(ii) chloride chloroform monosolvate hemihydrate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-11-01
description The title solvated salt, [NiCl(C10H8N2)2(H2O)]Cl·CHCl3·0.5H2O, contains a mononuclear NiII complex cation with 2,2′-bipyridine, chloride and aqua ligands forming a slightly distorted ClN4O octahedral coordination set. The charge of the cation is balanced by a chloride anion. In the crystal, half a water molecule and a chloroform solvent molecule are present per formula unit. Individual components are held together by O—H...Cl hydrogen bonding and π–π interactions.
topic crystal structure
nickel(II)
2,2′-bipyridine
octahedral coordination environment
url http://scripts.iucr.org/cgi-bin/paper?S2414314616018344
work_keys_str_mv AT eugeniavasileiadou aquabis22bipyridinek2nnchloridonickeliichloridechloroformmonosolvatehemihydrate
AT panagiotisaangaridis aquabis22bipyridinek2nnchloridonickeliichloridechloroformmonosolvatehemihydrate
AT raphaelgraptis aquabis22bipyridinek2nnchloridonickeliichloridechloroformmonosolvatehemihydrate
AT logeshmathivathanan aquabis22bipyridinek2nnchloridonickeliichloridechloroformmonosolvatehemihydrate
_version_ 1716775080573272064

Similar Items