Polymerization of sterically hindered a-olefins with single-site group 4 metal catalyst precursors

Polymerization of sterically hindered a-olefins with single-site group 4 metal catalyst precursors

A variety of group 4 metal catalytic systems (C2-symmetric {EBTHI}-, {SBI}-type zirconocene complexes (C2-1–4); C1-symmetric (C1-5–8) and Cs-symmetric (Cs-9) {Cp/Flu}-type zirconocene complexes; Cp*2ZrCl2 (Cp* 2-10)), half-metallocene complexes (CpTiCl3, HM-11), constrained-geometry (CGC-12) titaniu...

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Bibliographic Details
Main Authors: Gabriel Theurkauff, Katty Den Dauw, Olivier Miserque, Aurélien Vantomme, Jean-Michel Brusson, Jean-François Carpentier, Evgeny Kirillov
Format: Article
Language:English
Published: Iran Polymer and Petrochemical Institute 2016-01-01
Series:Polyolefins Journal
Subjects:
3-methylbut-1-ene
vinylcyclohexane
catalysis
polymerization
NMR analysis
Online Access:http://poj.ippi.ac.ir/article_1395_d02b7842eaaa9a9c594c82e2e12ebad2.pdf

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