Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II)
The title compound, (C9H9N2S)2[PdCl4], consists of two monoprotonated 2-amino-4-phenyl-1,3-thiazole molecules and one tetrachloridopalladate anion. The organic molecules exhibit a dihedral angle between the main rings planes of 31.82 (9)°. In the anion, the PdII atom is located on a crystallographic...
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doaj-b3961e5aa00a41fbbaa0b66b98721db42020-11-24T22:09:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-08-01708m295m29510.1107/S1600536814015360pj2013Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II)Reyna Reyes-Martínez0Rubén M. Carballo1Gonzalo J. Mena-Rejón2Simón Hernández-Ortega3David Cáceres-Castillo4Facultad de Química, Universidad Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP97150, Mérida, Yucatán, MexicoFacultad de Química, Universidad Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP97150, Mérida, Yucatán, MexicoFacultad de Química, Universidad Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP97150, Mérida, Yucatán, MexicoInstituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF, 04510, MexicoFacultad de Química, Universidad Autónoma de Yucatán, Calle 41 No. 421, Col. Industrial, CP97150, Mérida, Yucatán, MexicoThe title compound, (C9H9N2S)2[PdCl4], consists of two monoprotonated 2-amino-4-phenyl-1,3-thiazole molecules and one tetrachloridopalladate anion. The organic molecules exhibit a dihedral angle between the main rings planes of 31.82 (9)°. In the anion, the PdII atom is located on a crystallographic centre of symmetry with a square-planar geometry. In the crystal, the anions and cations are connected through bifurcated N—H...Cl hydrogen bonds, and these interactions lead to hydrogen-bonded tapes of cations and anions along [100].http://scripts.iucr.org/cgi-bin/paper?S1600536814015360crystal structure |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Reyna Reyes-Martínez Rubén M. Carballo Gonzalo J. Mena-Rejón Simón Hernández-Ortega David Cáceres-Castillo |
spellingShingle |
Reyna Reyes-Martínez Rubén M. Carballo Gonzalo J. Mena-Rejón Simón Hernández-Ortega David Cáceres-Castillo Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) Acta Crystallographica Section E crystal structure |
author_facet |
Reyna Reyes-Martínez Rubén M. Carballo Gonzalo J. Mena-Rejón Simón Hernández-Ortega David Cáceres-Castillo |
author_sort |
Reyna Reyes-Martínez |
title |
Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
title_short |
Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
title_full |
Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
title_fullStr |
Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
title_full_unstemmed |
Bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(II) |
title_sort |
bis(2-amino-4-phenyl-1,3-thiazol-3-ium) tetrachloridopalladate(ii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2014-08-01 |
description |
The title compound, (C9H9N2S)2[PdCl4], consists of two monoprotonated 2-amino-4-phenyl-1,3-thiazole molecules and one tetrachloridopalladate anion. The organic molecules exhibit a dihedral angle between the main rings planes of 31.82 (9)°. In the anion, the PdII atom is located on a crystallographic centre of symmetry with a square-planar geometry. In the crystal, the anions and cations are connected through bifurcated N—H...Cl hydrogen bonds, and these interactions lead to hydrogen-bonded tapes of cations and anions along [100]. |
topic |
crystal structure |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814015360 |
work_keys_str_mv |
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1725812043460640768 |