New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations

New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations

New Cd(II) and Hg(II) complexes of previously known five dithiophosphonic acids ((p-MeO-C6H4)PS(SH)(OR), HLn, (n= 1-5); R= 3-pentyl-, HL1; R=1-phenyl-1-propyl-, HL2; R= 4-tert-butyl benzyl-, HL3; R= diphenylmethyl-, HL4; R= 4-tert- butyl cyclohexyl-, HL5) were prepared and characterized. To do this...

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Main Authors: Ertuğrul Gazi SAĞLAM, Elif BULAT, Nurcan ACAR, İbrahim DEMİREL
Format: Article
Language:English
Published: Turkish Chemical Society 2020-02-01
Series:Journal of the Turkish Chemical Society, Section A: Chemistry
Subjects:
dithiophosphonic acid
phosphonodthioic acid
dithiophosphonate complexes
Online Access:https://dergipark.org.tr/en/pub/jotcsa/issue/49279/565642
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spelling doaj-b35b4514ae1d4c919741a3c809d8fccc2020-11-25T02:56:53ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202020-02-01714964https://doi.org/10.18596/jotcsa.565642New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and CharacterizationsErtuğrul Gazi SAĞLAM0https://orcid.org/0000-0002-7719-3934Elif BULAT 1https://orcid.org/0000-0002-2164-3641Nurcan ACAR2https://orcid.org/0000-0003-3531-9073İbrahim DEMİREL3https://orcid.org/0000-0002-8435-8434Yozgat Bozok University, Faculty of ScienceYozgat Bozok University, Institute of ScienceANKARA UNIVERSITY, FACULTY OF SCIENCEYozgat Bozok University, Institute of Science New Cd(II) and Hg(II) complexes of previously known five dithiophosphonic acids ((p-MeO-C6H4)PS(SH)(OR), HLn, (n= 1-5); R= 3-pentyl-, HL1; R=1-phenyl-1-propyl-, HL2; R= 4-tert-butyl benzyl-, HL3; R= diphenylmethyl-, HL4; R= 4-tert- butyl cyclohexyl-, HL5) were prepared and characterized. To do this, the dithiophosphonic acids involved were treated with stoichiometric amount of the corresponding metal salts in methyl alcohol. The complexes came of as powdery crystals and were recrystallized from chloroform. The pure complexes were characterized by using elemental analyses as well as mass-(ESI), FTIR-, Raman-, NMR- (1H, 13C, 31P) spectroscopies. https://dergipark.org.tr/en/pub/jotcsa/issue/49279/565642dithiophosphonic acidphosphonodthioic aciddithiophosphonate complexes
collection DOAJ
language English
format Article
sources DOAJ
author Ertuğrul Gazi SAĞLAM
Elif BULAT
Nurcan ACAR
İbrahim DEMİREL
spellingShingle Ertuğrul Gazi SAĞLAM
Elif BULAT
Nurcan ACAR
İbrahim DEMİREL
New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations
Journal of the Turkish Chemical Society, Section A: Chemistry
dithiophosphonic acid
phosphonodthioic acid
dithiophosphonate complexes
author_facet Ertuğrul Gazi SAĞLAM
Elif BULAT
Nurcan ACAR
İbrahim DEMİREL
author_sort Ertuğrul Gazi SAĞLAM
title New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations
title_short New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations
title_full New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations
title_fullStr New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations
title_full_unstemmed New Homodinuclear Alkyl and Aryl Dithiophosphonato Cd(II) and Hg(II) complexes: Syntheses and Characterizations
title_sort new homodinuclear alkyl and aryl dithiophosphonato cd(ii) and hg(ii) complexes: syntheses and characterizations
publisher Turkish Chemical Society
series Journal of the Turkish Chemical Society, Section A: Chemistry
issn 2149-0120
publishDate 2020-02-01
description New Cd(II) and Hg(II) complexes of previously known five dithiophosphonic acids ((p-MeO-C6H4)PS(SH)(OR), HLn, (n= 1-5); R= 3-pentyl-, HL1; R=1-phenyl-1-propyl-, HL2; R= 4-tert-butyl benzyl-, HL3; R= diphenylmethyl-, HL4; R= 4-tert- butyl cyclohexyl-, HL5) were prepared and characterized. To do this, the dithiophosphonic acids involved were treated with stoichiometric amount of the corresponding metal salts in methyl alcohol. The complexes came of as powdery crystals and were recrystallized from chloroform. The pure complexes were characterized by using elemental analyses as well as mass-(ESI), FTIR-, Raman-, NMR- (1H, 13C, 31P) spectroscopies.
topic dithiophosphonic acid
phosphonodthioic acid
dithiophosphonate complexes
url https://dergipark.org.tr/en/pub/jotcsa/issue/49279/565642
work_keys_str_mv AT ertugrulgazisaglam newhomodinuclearalkylandaryldithiophosphonatocdiiandhgiicomplexessynthesesandcharacterizations
AT elifbulat newhomodinuclearalkylandaryldithiophosphonatocdiiandhgiicomplexessynthesesandcharacterizations
AT nurcanacar newhomodinuclearalkylandaryldithiophosphonatocdiiandhgiicomplexessynthesesandcharacterizations
AT ibrahimdemirel newhomodinuclearalkylandaryldithiophosphonatocdiiandhgiicomplexessynthesesandcharacterizations
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