3-Chloro-N-(diphenylcarbamothioyl)benzamide
In the title compound, C20H15ClN2OS, the bond lengths and angles in the thiourea group are typical of thiourea derivatives. The C—N bond lengths in the center of the molecule are shorter than the normal C—N single bond due to the resonance effects in this part of the molecule. Th...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809001639 |
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doaj-b33cabeaf7ad495fbfba3e1e9119b14f2020-11-25T01:27:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652o351o35210.1107/S16005368090016393-Chloro-N-(diphenylcarbamothioyl)benzamideHakan ArslanNevzat KülcüUlrich FlörkeGün BinzetIn the title compound, C20H15ClN2OS, the bond lengths and angles in the thiourea group are typical of thiourea derivatives. The C—N bond lengths in the center of the molecule are shorter than the normal C—N single bond due to the resonance effects in this part of the molecule. The conformation of the title molecule with respect to the thiocarbonyl and carbonyl groups is twisted, as reflected by the C—N—C—O and C—N—C—N torsion angles of −4.4 (6) and −53.3 (5)°, respectively. Pairs of the molecules are linked into centrosymmetric dimers, stacked along the c axis via intermolecular N—H...S interactions. There are also weak intermolecular C—H...O and C—H...S contacts in the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809001639 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Hakan Arslan Nevzat Külcü Ulrich Flörke Gün Binzet |
| spellingShingle |
Hakan Arslan Nevzat Külcü Ulrich Flörke Gün Binzet 3-Chloro-N-(diphenylcarbamothioyl)benzamide Acta Crystallographica Section E |
| author_facet |
Hakan Arslan Nevzat Külcü Ulrich Flörke Gün Binzet |
| author_sort |
Hakan Arslan |
| title |
3-Chloro-N-(diphenylcarbamothioyl)benzamide |
| title_short |
3-Chloro-N-(diphenylcarbamothioyl)benzamide |
| title_full |
3-Chloro-N-(diphenylcarbamothioyl)benzamide |
| title_fullStr |
3-Chloro-N-(diphenylcarbamothioyl)benzamide |
| title_full_unstemmed |
3-Chloro-N-(diphenylcarbamothioyl)benzamide |
| title_sort |
3-chloro-n-(diphenylcarbamothioyl)benzamide |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-02-01 |
| description |
In the title compound, C20H15ClN2OS, the bond lengths and angles in the thiourea group are typical of thiourea derivatives. The C—N bond lengths in the center of the molecule are shorter than the normal C—N single bond due to the resonance effects in this part of the molecule. The conformation of the title molecule with respect to the thiocarbonyl and carbonyl groups is twisted, as reflected by the C—N—C—O and C—N—C—N torsion angles of −4.4 (6) and −53.3 (5)°, respectively. Pairs of the molecules are linked into centrosymmetric dimers, stacked along the c axis via intermolecular N—H...S interactions. There are also weak intermolecular C—H...O and C—H...S contacts in the structure. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809001639 |
| work_keys_str_mv |
AT hakanarslan 3chlorondiphenylcarbamothioylbenzamide AT nevzatk252lc252 3chlorondiphenylcarbamothioylbenzamide AT ulrichfl246rke 3chlorondiphenylcarbamothioylbenzamide AT g252nbinzet 3chlorondiphenylcarbamothioylbenzamide |
| _version_ |
1725106552418861056 |