(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione

(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione

The title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative. The crystal structure of the racemic (R,R/S,S) modification reveals two near-orthogonal five-membered heterocyclic ring systems, each in an e...

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Bibliographic Details
Main Authors: Craig M. Forsyth, Zohreh Nazarian
Format: Article
Language:English
Published: International Union of Crystallography 2019-04-01
Series:IUCrData
Subjects:
crystal structure
spirocyclic compounds
cyclization reactions
oxazolidinone
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314619005200
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spelling doaj-b2ebf11225ef49f48bbc26055432d8892020-11-24T21:51:08ZengInternational Union of CrystallographyIUCrData2414-31462019-04-0144x19052010.1107/S2414314619005200nk4001(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dioneCraig M. Forsyth0Zohreh Nazarian1School of Chemistry, Monash University, Clayton 3800, AustraliaSchool of Chemistry, Monash University, Clayton 3800, AustraliaThe title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative. The crystal structure of the racemic (R,R/S,S) modification reveals two near-orthogonal five-membered heterocyclic ring systems, each in an envelope configuration.http://scripts.iucr.org/cgi-bin/paper?S2414314619005200crystal structurespirocyclic compoundscyclization reactionsoxazolidinone
collection DOAJ
language English
format Article
sources DOAJ
author Craig M. Forsyth
Zohreh Nazarian
spellingShingle Craig M. Forsyth
Zohreh Nazarian
(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
IUCrData
crystal structure
spirocyclic compounds
cyclization reactions
oxazolidinone
author_facet Craig M. Forsyth
Zohreh Nazarian
author_sort Craig M. Forsyth
title (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
title_short (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
title_full (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
title_fullStr (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
title_full_unstemmed (R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
title_sort (r,r/s,s)-9-benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2019-04-01
description The title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative. The crystal structure of the racemic (R,R/S,S) modification reveals two near-orthogonal five-membered heterocyclic ring systems, each in an envelope configuration.
topic crystal structure
spirocyclic compounds
cyclization reactions
oxazolidinone
url http://scripts.iucr.org/cgi-bin/paper?S2414314619005200
work_keys_str_mv AT craigmforsyth rrss9benzyl3methyl7phenyl16dioxa39diazaspiro44nonane28dione
AT zohrehnazarian rrss9benzyl3methyl7phenyl16dioxa39diazaspiro44nonane28dione
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